Observations of type Ia supernovae (SNe Ia) admit white dwarfs (WDs) with masses as high as 2.3−2.6M⊙, surpassing in this way the mass limit of WDs established by Chandrasekhar (1.44M⊙). Within the scope of pseudo‐complex general relativity (pc‐GR), we investigate a possible mechanism for such a hypothesis, using a very simple model for the WD matter, which consists in our approach of ionized hydrogen and helium nuclei (nucleons) and electrons. In pc‐GR, the field equations have an extra term compared to the field equations of Einstein's general relativity. This additional term is associated with the nature of spacetime, of repulsive character, which is believed to halt the gravitational attractive collapse of matter distributions in the evolution process of compact stars. This additional term arises from microscale phenomena due to vacuum fluctuations, which simulate the presence of dark energy in the Universe. In a more conventional theoretical description of a WD, the electron degeneracy pressure ultimately stabilizes the star against collapse. In this paper, we explore the presence of this additional term of pc‐GR and study the role of dark energy in the structure of WDs, constituted by nucleons and electrons and held together by the presence of the gravitational interaction, and superimposed on a repulsive background of dark energy. The corresponding versions of the Tolman–Oppenheimer–Volkoff (TOV) equations in the pc‐GR formalism are solved, and the mass–radius relations as well as the maximum mass of the WD star are determined for different parameter configurations.