In many plants the potassium contained in the tissues is almost completely water soluble (3,15,16, 18, 19,32) It is generally supposed that much of the potassium present in plants is in the form of salts of organic acids and that these acids and their salts constitute principal components of the buffer systems. A relationship between the total organic acids and the excess of cations over inorganic anions in tobacco leaves of different ages and base composition was shown by PUCHER, VICKERY, and WAKEMAN (22). PIERCE and APPLEMAN (21) grew several species of plants in the same nutrient medium and showed a general correlation between the excess of cations and the total organic acids. In these correlations, however, were ineluded both soluble and insoluble constituents, and variations in insoluble oxalate and calcium contributed much to the variations in the total bases and organic acids. ULRICH (33) has shown that the total organic acid content of sap expressed from barley roots may be varied by unequal absorption of cations and anions from the solution. An absorption of cations in excess of anions results in an in-