Relation of Volume Change to the Mechanism of Rubber Vulcanization

Williams, Ira

doi:10.1021/ie50295a013

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Vulcanization In Solution1

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1939

1943

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Article2

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“…Williams (41) found that the gelation time of cements of rubber, sulfur, zinc oxide, and P. P. D. was increased by increasing the amount of P. P. D., and that an excess of P. P. D. made it possible to disperse a gel after it had formed. He found that the time required to disperse vulcanized rubber on immersion in various accelerators was greatly increased by the addition of soluble zinc salts.…”

Section: Vulcanization In Solutionmentioning

confidence: 99%

Effect of Vulcanization on Rubber Structure. A Problem in Probabilities

Busse¹

1939

Ind. Eng. Chem.

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Section: Vulcanization In Solutionmentioning

confidence: 99%

Effect of Vulcanization on Rubber Structure. A Problem in Probabilities

Busse¹

1939

Ind. Eng. Chem.

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Wie der Schwefel im vulkanisierten Gummi gebunden ist

Amerongen¹,

Houwink²

1943

J. Prakt. Chem.

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Mit Hilfe von Molekülmodellen nach Stuart wird gezeigt, daß bei Schwefelbindung an Kautschuk von den intramolekularen Bindungen aus der Abb.3 nur die Nummern 1 und 4 bestehen können und von den intermolekularen Bindungen nur die Nummern 6, 7, 10 und 11 oder deren Variationen. Es wird weiter ein Reaktionsschema zur Erklärung der Bildung von intra‐ und intermolekularen Bindungen aus dem Kautschukmercaptan Nr. 1, wobei die Verbindungen 4 bzw. 10 entstehen mögen, geprüft.

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Relation of Volume Change to the Mechanism of Rubber Vulcanization

Cited by 2 publications

References 4 publications

Effect of Vulcanization on Rubber Structure. A Problem in Probabilities

Effect of Vulcanization on Rubber Structure. A Problem in Probabilities

Wie der Schwefel im vulkanisierten Gummi gebunden ist

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