BACKGROUND: At concentrations higher than 1 mg L −1 , 4-chlorophenol (4-CP) is very toxic to living organisms, and if ingested beyond the permitted concentration it causes health disorders such as cancer and mutation. This laboratory study investigates treatment of contaminated water laden with 4-CP using coconut shell charcoal (CSC) waste. Batch studies were conducted to study the effects of dose, pH, and equilibrium time on 4-CP removal. To improve 4-CP removal, surface modification of the adsorbent with TiO 2 , HNO 3 , and/or NaOH was undertaken.