Castaing’s successful implementation and application of the electron
probe microanalyzer in 1950 stimulated a flurry of development activity
around the world. The later versions of this instrument represented a truly
international effort, with significant contributions by scientists from
Europe, Asia, and North America. If the probe-forming system of the
instrument was its heart, the X-ray wavelength spectrometer was its soul.
This article reviews some of the history of spectrometer
developments—lthrough the “golden years” of microprobe development, namely
the dozen or so years following the publication of Castaing’s thesis, to the
present. The basic physics of spectrometer and crystal design is reviewed.
Early experimental devices, such as those developed by Castaing, Borovskii,
Wittry, Duncumb, and Ogilvie are reported. Examples of commercial
spectrometers such as those by ARL, MAC, Microspec, and Peak are described.
Recent developments such as the combination of grazing-incidence optics with
flat crystal spectrometers are noted, and the properties and uses of doubly
curved crystals are discussed. Finally, the continued development of doubly
curved crystal configurations, such as the “Wittry geometry” for scanning
monochromators, and point-to-point focusing diffractors for producing small
monochromatic X-ray probes to provide improved detection limits for
microanalysis are considered.