2003
DOI: 10.1086/377386
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Reduction of Thermodynamics: A Few Problems

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Cited by 3 publications
(2 citation statements)
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“…But the problem is that partition functions of finite systems do not have singularities: 'SM [statistical mechanics] represents the abrupt phase-changes of a system as singularities of its partition function. But no partition function of a finite system can have these singularities; only infinite systems can' (Yi 2003(Yi , 1032. The common solution of this problem of explaining phase transitions in statistical mechanics is to take the 'thermodynamic limit', which means to assume that the system in question consists of an infinite number of particles: 'Mathematical physics avoids this result by taking the thermodynamic limit, for it is possible for systems with infinite N to display singular behavior for non-vanishing partition functions' (Callender 2001, 549).…”
Section: Phenomenological Thermodynamics and Statistical Mechanicsmentioning
confidence: 99%
“…But the problem is that partition functions of finite systems do not have singularities: 'SM [statistical mechanics] represents the abrupt phase-changes of a system as singularities of its partition function. But no partition function of a finite system can have these singularities; only infinite systems can' (Yi 2003(Yi , 1032. The common solution of this problem of explaining phase transitions in statistical mechanics is to take the 'thermodynamic limit', which means to assume that the system in question consists of an infinite number of particles: 'Mathematical physics avoids this result by taking the thermodynamic limit, for it is possible for systems with infinite N to display singular behavior for non-vanishing partition functions' (Callender 2001, 549).…”
Section: Phenomenological Thermodynamics and Statistical Mechanicsmentioning
confidence: 99%
“…1 Now, it seems that reduction isn't all that smooth in chemistry and physics either (Yi, 2003, Schaffner, 2006, Hendry and Needham, 2007. Given this, biological kinds must be taken to bring additional trouble.…”
Section: The Targeted Positionmentioning
confidence: 99%