Abstract:The redox chemistry of Ce III DOTA in cage in carbonate solutions was studied using electrochemistry and radiolysis techniques (continuous radiolysis and pulse radiolysis). Spectroscopic measurements point out that the species present in the solutions at high bicarbonate concentrations are [Ce III DOTA(CO 3 )] 3− (or less plausible [Ce III DOTA-(HCO 3 )] 2− ) with the carbonate (bicarbonate) anion as the ninth ligand versus [Ce III DOTA(H 2 O)] − present in the absence of bicarbonate. Electrochemical results s… Show more
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