2021
DOI: 10.5254/rct.21.79971
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Recycling Behavior of Thermoreversibly Diels–alder Crosslinked Epm

Abstract: The recyclability of thermoreversibly Diels–Alder (DA) crosslinked EPM has been studied. The retro DA reaction dominates over the dehydration–aromatization process of the DA adduct. Moreover, a negative influence of air occurred as a result of a crosslinking in air flow. Nevertheless, rubber compounds prepared from EPM-g-furan and carbon black can be recycled several times without losing mechanical strength, a feature attributed to a strong antioxidant effect of the carbon black.

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Cited by 2 publications
(3 citation statements)
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“…7 The exceptional properties of smart materials enable their application in elds like drug delivery, 8 oil recovery, 9 sensors, 10 so actuators, 11 energy harvesting, 12,13 and self-healing materials. 14 Nowadays, sustainability is a crucial societal topic, especially in terms of polymer material pollution. A wise solution to this issue is found in the design of self-healing polymers.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…7 The exceptional properties of smart materials enable their application in elds like drug delivery, 8 oil recovery, 9 sensors, 10 so actuators, 11 energy harvesting, 12,13 and self-healing materials. 14 Nowadays, sustainability is a crucial societal topic, especially in terms of polymer material pollution. A wise solution to this issue is found in the design of self-healing polymers.…”
Section: Introductionmentioning
confidence: 99%
“…7 The exceptional properties of smart materials enable their application in fields like drug delivery, 8 oil recovery, 9 sensors, 10 soft actuators, 11 energy harvesting, 12,13 and self-healing materials. 14…”
Section: Introductionmentioning
confidence: 99%
“…Recently a reversible Diels–Alder (DA) reaction has been applied for thermoreversibly cross-linked rubber and thermosets . Nevertheless, some irreversible cross-linking reactions may take place under the same experimental conditions (high temperature) in which the de-cross-linking retro-DA reaction occurs . Moreover, for some manufacturing protocols, e.g., three-dimensional (3D) printing, photoinduced cross-linking is more preferable.…”
Section: Introductionmentioning
confidence: 99%