2016
DOI: 10.1002/jssc.201600808
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Recent progress of chiral stationary phases for separation of enantiomers in gas chromatography

Abstract: Chromatography techniques based on chiral stationary phases are widely used for the separation of enantiomers. In particular, gas chromatography has developed rapidly in recent years due to its merits such as fast analysis speed, lower consumption of stationary phases and analytes, higher column efficiency, making it a better choice for chiral separation in diverse industries. This article summarizes recent progress of novel chiral stationary phases based on cyclofructan derivatives and chiral porous materials… Show more

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Cited by 104 publications
(54 citation statements)
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References 122 publications
(163 reference statements)
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“…The isomer pX is widely used as the key raw material in the production of terephthalic acid. [10][11][12] As an emerging family of porous materials with zeolite topologies, metal-organic frameworks (MOFs) possess well-defined channels or cavities that are constructed by metal cations/clusters and functional organic linkers, making them highly suitable for diverse adsorption applications, [13][14][15][16][17][18][19] such as xylenes separation. 7 The slight differences in the boiling points of the xylene isomers lead to the difficulty and inefficiency of distillation separation processes.…”
Section: Introductionmentioning
confidence: 99%
“…The isomer pX is widely used as the key raw material in the production of terephthalic acid. [10][11][12] As an emerging family of porous materials with zeolite topologies, metal-organic frameworks (MOFs) possess well-defined channels or cavities that are constructed by metal cations/clusters and functional organic linkers, making them highly suitable for diverse adsorption applications, [13][14][15][16][17][18][19] such as xylenes separation. 7 The slight differences in the boiling points of the xylene isomers lead to the difficulty and inefficiency of distillation separation processes.…”
Section: Introductionmentioning
confidence: 99%
“…[1] Theseparation of racemic compounds has long been of great significance,especially for pharmaceutical and medicinal applications, [2,3] which has spurred continuous interest in the exploration of new materials/approaches for efficient separation of enantiomers. [1] Theseparation of racemic compounds has long been of great significance,especially for pharmaceutical and medicinal applications, [2,3] which has spurred continuous interest in the exploration of new materials/approaches for efficient separation of enantiomers.…”
mentioning
confidence: 99%
“…Ethyl group forms a hydrophobic interaction site. [41][42][43] (S)-MA shows stronger overall binding and convenient stereochemical approaches to CSP. Hydrophobic ethyl groups form weak Van der Waals interactions with analytes.…”
Section: Chiral Separationmentioning
confidence: 99%