Recent developments in phosphorus based flame retardant coatings for textiles: Synthesis, applications and performance

Özer, Merve S.; Gaan, Sabyasachi

doi:10.1016/j.porgcoat.2022.107027

Cited by 49 publications

(16 citation statements)

References 163 publications

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“…Flame retardancy is one of the critical performance parameters to be considered in the design of polymers [ 132 ]. In industrial and academic applications, phosphorus-containing compounds play a crucial role in polymer flame retardants (FRs), as they are less harmful to the environment compared to the persistent and possibly bioaccumulating halogen-based flame retardants [ 133 ]. According to a 2019 market study [ 134 ], phosphorus-based compounds represent the third most used family of the FRs ( Figure 16 ).…”

Section: Properties and Applications Of Polyphosphodiestersmentioning

confidence: 99%

Design, Synthesis and Actual Applications of the Polymers Containing Acidic P–OH Fragments: Part 1. Polyphosphodiesters

Nifant’ev

Ivchenko

2022

IJMS

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Among natural and synthetic polymers, main-chain phosphorus-containing polyacids (PCPAs) (polyphosphodiesters), stand in a unique position at the intersection of chemistry, physics, biology and medicine. The structural similarity of polyphosphodiesters PCPAs to natural nucleic and teichoic acids, their biocompatibility, mimicking to biomolecules providing the ‘stealth effect’, high bone mineral affinity of polyphosphodiesters resulting in biomineralization at physiological conditions, and adjustable hydrolytic stability of polyphosphodiesters are the basis for various biomedical, industrial and household applications of this type of polymers. In the present review, we discuss the synthesis, properties and actual applications of polyphosphodiesters.

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Section: Properties and Applications Of Polyphosphodiestersmentioning

confidence: 99%

Design, Synthesis and Actual Applications of the Polymers Containing Acidic P–OH Fragments: Part 1. Polyphosphodiesters

Nifant’ev

Ivchenko

2022

IJMS

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“…The phosphorus-containing FRs surpass halogen-based FRs in safety and are being intensively researched [ 12 ]. In a recent review of Özer and Gaan, devoted to phosphorus-based flame retardant coatings for textiles [ 174 ], low-MW compounds have mainly been described.…”

Section: Properties and Applications Of Sidechain Pcpasmentioning

confidence: 99%

Design, Synthesis and Actual Applications of the Polymers Containing Acidic P–OH Fragments: Part 2—Sidechain Phosphorus-Containing Polyacids

Nifant’ev

Ivchenko

2023

IJMS

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Macromolecules containing acidic fragments in side-groups—polyacids—occupy a special place among synthetic polymers. Properties and applications of polyacids are directly related to the chemical structure of macromolecules: the nature of the acidic groups, polymer backbone, and spacers between the main chain and acidic groups. The chemical nature of the phosphorus results in the diversity of acidic >P(O)OH fragments in sidechain phosphorus-containing polyacids (PCPAs) that can be derivatives of phosphoric or phosphinic acids. Sidechain PCPAs have many similarities with other polyacids. However, due to the relatively high acidity of –P(O)(OH)2 fragment, bone and mineral affinity, and biocompatibility, sidechain PCPAs have immense potential for diverse applications. Synthetic approaches to sidechain PCPAs also have their own specifics. All these issues are discussed in the present review.

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“…Accordingly, by using flammability parameters obtained from a fire test, such as LOI value, synergistic effectivity can be calculated to express whether a synergism occurs between two species. The formula for SE calculation is shown below [31].…”

Section: Quantitative Expression Of Synergism Between Dp and Melaminementioning

confidence: 99%

Flame retardant back-coated PET fabric with DOPO-based environmentally friendly formulations

Özer

Wesemann

Gaan

2023

Progress in Organic Coatings

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Recent developments in phosphorus based flame retardant coatings for textiles: Synthesis, applications and performance

Cited by 49 publications

References 163 publications

Design, Synthesis and Actual Applications of the Polymers Containing Acidic P–OH Fragments: Part 1. Polyphosphodiesters

Design, Synthesis and Actual Applications of the Polymers Containing Acidic P–OH Fragments: Part 1. Polyphosphodiesters

Design, Synthesis and Actual Applications of the Polymers Containing Acidic P–OH Fragments: Part 2—Sidechain Phosphorus-Containing Polyacids

Flame retardant back-coated PET fabric with DOPO-based environmentally friendly formulations

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