The nature of metal-semiconductor contacts plays a pivotal role in every electronic (and optoelectronic) device, [1] since it controls charge injection into the devices, and, through this, carriers populations, transport regimes, and ultimately, in luminescent devices, the quantum efficiency for conversion of electrons into photons. Such considerations are also true for polymer-based (opto)electronic devices such as PLEDs that show particular promise for cheap fabrication of full-color displays over large areas. A significant effort in this context has been devoted to the development of blue-emitters, [2] that pose the biggest challenge, since the increased energy gap with respect to green and red emitters translates into a greater difficulty in minimizing charge-injection barriers, and in ensuring sufficient stability and durability. Following the success of poly(9,9-dioctylfluorene) as a highly efficient blue emitter, [3] polyfluorene-based homo-and co-polymers (including for example TFB and PFB, see Fig.