2020
DOI: 10.1002/smtd.201900749
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Recent Advances of Gas Transport Channels Constructed with Different Dimensional Nanomaterials in Mixed‐Matrix Membranes for CO2 Separation

Abstract: Most CO2 separation membranes are polymeric membranes owing to low cost and easy processability. Nevertheless, conventional polymeric membranes may suffer from a compromise between permeability and selectivity represented by the Robeson upper bound curves. Mixed‐matrix membranes (MMMs), prepared by adding nanomaterials in polymer matrices, can achieve both high gas permeability and selectivity with the potential for future applications. This review summarizes gas transport channels constructed with different d… Show more

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Cited by 50 publications
(20 citation statements)
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“…Among these efforts, polymer blends and mixed matrix membranes (MMMs) are the popular approaches because they are simple and effective [ 19 , 20 ]. Particularly, MMMs, which incorporate inorganic particles in the continuous phase of the polymer matrix, have gained growing interests [ 9 , 20 , 21 , 22 ]. In MMMs, the polymeric matrix offers low cost and easy processability as the major benefits, while inorganic components exhibit high permeability, selectivity, and good thermal stability.…”
Section: Introductionmentioning
confidence: 99%
“…Among these efforts, polymer blends and mixed matrix membranes (MMMs) are the popular approaches because they are simple and effective [ 19 , 20 ]. Particularly, MMMs, which incorporate inorganic particles in the continuous phase of the polymer matrix, have gained growing interests [ 9 , 20 , 21 , 22 ]. In MMMs, the polymeric matrix offers low cost and easy processability as the major benefits, while inorganic components exhibit high permeability, selectivity, and good thermal stability.…”
Section: Introductionmentioning
confidence: 99%
“…Organic membranes can be formed of organic polymers or cellulose. It is of importance to know that most membranes for industrial usages are organic membranes made of polymeric materials which are called polymeric membranes owing to their easy and low‐cost processing, large versatile polymers available in the market, and the potential to synthesize easily many new polymers 58–60. Polymeric materials are either glassy or rubbery based on their glass transition and operating temperatures.…”
Section: Membrane Categorizationmentioning
confidence: 99%
“…Limitadas a la relación de compensación entre permeabilidad y selectividad, las membranas de matriz mixta han atraído una gran atención y surgieron como un enfoque prometedor para resolver este problema. Al introducir nanomateriales con estructuras finamente controladas en la matriz polimérica, las membranas de matriz mixta integran la procesabilidad de los polímeros con excelentes propiedades de separación de las cargas [41]. A la fecha, se han reportado varios nanomateriales como relleno en las membranas de matriz mixta, tales como: 1) nanotubos de carbono, los cuales aumentan la permeabilidad del dióxido de carbono y la selectividad de la membrana [42], 2) óxido de grafeno, el cual permite la interacción del CO2 con el oxígeno contenido en su estructura, mejorando la separación de CO2/CH4 [43] y 3) zeolitas, las cuales su modifican su estructura superficial mejorando su compatibilidad con la matriz orgánica, reflejada ésta en un aumento en la selectividad hacia el CO2 [44].…”
Section: Catiínico Y Anionicounclassified