Recent Advances in the Synthesis and Applications of Inorganic Polymer

Pitcher, Michael W.; Arslan, Yasin; Edinç, Pelin; Kartal, Müjgan; Masjedi, Mehdi; Metin, Önder; Şen, Fatih; Türkarslan, Özlem; Yiğitsoy, Başak

doi:10.1080/10426500701540431

Cited by 9 publications

(10 citation statements)

References 76 publications

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“…17 For example, a composite between an IFE and an organic polymer satisfies the need for high mechanical strength, high thermal stability, piezoelectricity, pyroelectricity, and energy storage properties compared to a pure organic polymer, which opens a new window for energy harvesting, IR sensing, and energy storage devices. 1,[7][8][9] Additionally, organic polymers lack thermal stability, undergo degradation, produce toxic smoke upon burning, and, last but not least, are derived from a natural source such as petroleum. 1,7 As a remedial solution, researchers are trying to develop IFE-based flexible devices on inorganic polymers (including polydimethylsiloxane (PDMS)) and plastic substrates (including mica).…”

Section: Venkata Sreenivas Pulimentioning

confidence: 99%

“…1,[7][8][9] Additionally, organic polymers lack thermal stability, undergo degradation, produce toxic smoke upon burning, and, last but not least, are derived from a natural source such as petroleum. 1,7 As a remedial solution, researchers are trying to develop IFE-based flexible devices on inorganic polymers (including polydimethylsiloxane (PDMS)) and plastic substrates (including mica). 7 Therefore, it is important to summarize recent developments in the field of IFEs and the possible promising combination of these materials with organic polymers.…”

Section: Venkata Sreenivas Pulimentioning

confidence: 99%

“…1,7 As a remedial solution, researchers are trying to develop IFE-based flexible devices on inorganic polymers (including polydimethylsiloxane (PDMS)) and plastic substrates (including mica). 7 Therefore, it is important to summarize recent developments in the field of IFEs and the possible promising combination of these materials with organic polymers.…”

Section: Venkata Sreenivas Pulimentioning

confidence: 99%

“…2 In fact, recently, dielectric materials have been receiving a great deal of attention in the areas of energy harvesting, sensing, and energy storage applications. [3][4][5][6][7][8][9][10][11][12][13] Fig. 1 shows the domains where dielectric materials make their mark.…”

Section: Introductionmentioning

confidence: 99%

“…But there are several intrinsic parameters that determine the performance of a dielectric material as an energy harvester, an infra-red (IR) sensor, or an energy storage capacitor. [3][4][5][6][7][8][9][10][11][12][13] For example, energy harvesting applications require dielectric materials that can convert energy from mechanical vibrations and heat fluctuations into electrical energy. [1][2][3][4] On the other hand, IR sensing applications demand dielectric materials with a large spontaneous polarization change w.r.t.…”

Section: Introductionmentioning

confidence: 99%

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Inorganic ferroelectric thin films and their composites for flexible electronic and energy device applications: current progress and perspectives

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Section: Venkata Sreenivas Pulimentioning

confidence: 99%

Section: Venkata Sreenivas Pulimentioning

confidence: 99%

Section: Venkata Sreenivas Pulimentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Inorganic ferroelectric thin films and their composites for flexible electronic and energy device applications: current progress and perspectives

et al. 2023

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Polyphosphazenes – Synthetically Versatile Block Copolymers (“Multi‐Tool”) for Self‐Assembly

2018

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This microreview outlines recent advances on the synthesis and self-assembly of polyphosphazene diblock copolymers, a class of versatile polymers (Multi-Tool) able to generate a great variety of different well-defined nanomorphologies. Particular focus is placed on the synthesis of linear block copolymers composed of two polyphosphazene chains (PP-b-PP′), or hybrid polymers combining one PP chain with a non- [a] 2484 Gabino A. Carriedo (Ph D in 1981) is Full-time Professor of Inorganic Chemistry in the University of Oviedo since 1989. His research interest in synthetic chemistry has included coordination and organometallic chemistry, electrochemistry and polymer chemistry. Since 1995 he has focused in designed syntheses of phosphazene polymers and their chemical derivatization. (2012) developing new synthetic methodologies in organic chemistry by means of organometallic carbene reagents under the supervision of Prof. J. Barluenga and Prof. J. Flórez. After, she moved to the group of D. Dixon (Oxford) to explore new catalytic asymmetric methodologies. She returned to the University of Oviedo in 2015 as Post-doctoral research assistant. Nowadays, her research is focused on the synthesis and self-assembly of new material based on polyphosphazene polymers. 2488 Scheme 4. Synthesis of linear polyphosphazene diblock copolymers 28-35 by sequential living cationic polymerization of phosphoranimines of type (X)(R 1 )(R 2 )P=N-SiMe 3 over living chains of 1[PCl 6 ]. Scheme 5. Sequential living polymerization of phosphoranimine 36 by using active end-groups of polyphosphazene 17 as initiators. The synthesis of BCP 37 is suggested in ref. 47. methodologies afforded the PP-b-PS copolymers with moderately good yields (< 60 %) and polydispersities (< 1.3). Scheme 10. Synthetic routes to polyphosphazene-b-polystyrene, PP-b-PS, via macromolecular coupling of telechelic (PS) n -P(R) 2 = N-SiMe 3 , 53 and 54, with an end-capped poly(dichlorophosphazene) 55 (Ec. c). Raquel de la Campa was born in Cangas del Narcea (Asturias, Spain) in 1981. He obtained his PhD at the University of OviedoRecently, our group developed a very convenient synthesis for linear hybrid PP-b-PS block copolymers (Scheme 11). [63] Using the lithiated-phosphine 56 as initiator, the anionic polymerization of styrene gave the telechelic polystyrene 57 (PS m -PPh 2 ) after quenching the reaction with Cl-SiMe 3 . The chlorination of Scheme 11. Synthetic routes to polyphosphazene-b-polystyrene, PP-b-PS (60), via lithiated-phosphine initiator 56, and macromolecular initiator 58.2492 57 led to PS m -PPh 2 Cl 2 (58) having -PPh 2 Cl 2 end-groups that initiate the polymerization of Cl 3 P=N-SiMe 3 (6) producing the block copolymer [N=PCl 2 ] n -PS m (59). The macromolecular substitution of the chlorine atoms by -OCH 2 CF 3 groups yielded the block copolymer [N=P(OCH 2 CF 3 ) 2 ] n -PS m (60) having crystalline PP blocks. This synthetic methodology afforded the hybrid PP-b-PS block copolymer in 70 % yield and with narrower polydispersities (PDI = 1.2) than those of the...

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31P MAS NMR Spectroscopy of Hexachlorocyclotriphosphazene at Different Stages During Thermal Ring-Opening Polymerization

Borisov

Hazendonk

Hayes

2009

J Inorg Organomet Polym

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Recent Advances in the Synthesis and Applications of Inorganic Polymer

Cited by 9 publications

References 76 publications

Inorganic ferroelectric thin films and their composites for flexible electronic and energy device applications: current progress and perspectives

Inorganic ferroelectric thin films and their composites for flexible electronic and energy device applications: current progress and perspectives

Polyphosphazenes – Synthetically Versatile Block Copolymers (“Multi‐Tool”) for Self‐Assembly

31P MAS NMR Spectroscopy of Hexachlorocyclotriphosphazene at Different Stages During Thermal Ring-Opening Polymerization

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