1960
DOI: 10.1139/v60-313
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REARRANGEMENT STUDIES WITH C14. X. ETHANOL-2-C14 FROM THE IRRADIATION OF ETHANOL-1-C 14 WITH Co60 GAMMA RAYS

Abstract: The irradiation of aqueous solutior~s of ethanol-1-C1", containing about 2% ethanol by weight, with up to 58.0 million rads of CoGo y-rays lecl to the formation of up to 0.49y0 ethanol-2-C14 in the alcohol recovered after irradiation. The G value of this isotope position rearrangenlent was about 0.04 and amounted to approximately 2% of the G value for the total amount of ethanol decomposed. Possible mechanisms for the rearrangement are discussed.In a review in 1956, Collinson and Swallow (1) pointed out that r… Show more

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