1972
DOI: 10.1070/rc1972v041n09abeh002090
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Intramolecular Rearrangements of Hydrocarbon Radicals in the Gas Phase

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Cited by 5 publications
(2 citation statements)
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“…In a series of papers from the 1960s on strategically deuterated, isopropyl and isobutyl radicals, Jackson and McNesby set upper limits on the amount of 1,2 H-shifts and C–H β-scission at (472 to 813) K of 7% for isopropyl and 1% for isobutyl and argued that these upper limits were lower than other literature values because their experiments were free from nonthermal photochemistry . Multiple other researchers claimed significant 1,2 H-shift branching ratios for decades afterward. ,, These claims were usually based, however, on the detection of compounds that could easily be produced from side chemistry, including methane and ethene. , …”
Section: Discussionmentioning
confidence: 99%
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“…In a series of papers from the 1960s on strategically deuterated, isopropyl and isobutyl radicals, Jackson and McNesby set upper limits on the amount of 1,2 H-shifts and C–H β-scission at (472 to 813) K of 7% for isopropyl and 1% for isobutyl and argued that these upper limits were lower than other literature values because their experiments were free from nonthermal photochemistry . Multiple other researchers claimed significant 1,2 H-shift branching ratios for decades afterward. ,, These claims were usually based, however, on the detection of compounds that could easily be produced from side chemistry, including methane and ethene. , …”
Section: Discussionmentioning
confidence: 99%
“…9 Multiple other researchers claimed significant 1,2 H-shift branching ratios for decades afterward. [24][25][26]78,79 These claims were usually based, however, on the detection of compounds that could easily be produced from side chemistry, including methane and ethene. 24,25 More recent experimental work by Yamauchi et al 23 in 1999 provides strong evidence against 1,2 H-shifts and competitive C−H β-scissions.…”
Section: Discussionmentioning
confidence: 99%