Reactivity of [Re2(CO)8(MeCN)2] With 1-vinylimidazole: X-ray Structures of [Re2(CO)8{η 1-NC3H3N(CH=CH2)}2] and [ReCl2(CO)2{η 1-NC3H3N(CH=CH2)}2]

Ghosh, Shishir; Ahmed, Faruque; Haworth, Daniel T.; Kabir, Shariff E.

doi:10.1007/s10870-009-9536-x

Cited by 10 publications

(1 citation statement)

References 30 publications

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“…Additionally, Cu(II) and Cd(II) coordination polymers containing these ligands have not been investigated in the literature. Vim has important properties for polymerization and reactivity [37,38] and can coordinate to metal ions via the ring nitrogen atom [39,40]. The polymeric complexes of Co(II), Ni(II), Cu(II), Zn(II), and Cd(II) ions containing vim were studied in our previous works [41][42][43][44].…”

Section: Introductionmentioning

confidence: 99%

Cu(II) and Cd(II) coordination polymers derived from pyrazine-2,3-dicarboxylato and 1-vinylimidazole ligands: Synthesis, characterization and hydrogen storage capacities

Gördük

Yilmaz

Andaç

2019

Maced. J. Chem. Chem. Eng.

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In this study, two new coordination polymers of Cu(II) and Cd(II) ions with pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole were synthesized. The structures of these coordination polymers were characterized with elemental analysis, infrared spectroscopy, thermal analysis, powder X-ray diffraction, and magnetic susceptibility techniques. According to the results of the thermal analysis, the coordination polymers that contained water molecules decomposed below 100 °C, and the final products for both coordination polymers were the related metal oxides in an oxygen atmosphere. Powder X-ray diffraction analysis revealed that the coordination polymers were in the crystalline form. The hydrogen storage capacities and surface areas of the coordination polymers were also determined. The highest hydrogen storage capacities were measured as 296 ml/g for the Cu(II) coordination polymer and 330 ml/g for the Cd(II) coordination polymer at approximately 75 bar and 75 K.

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Section: Introductionmentioning

confidence: 99%

Cu(II) and Cd(II) coordination polymers derived from pyrazine-2,3-dicarboxylato and 1-vinylimidazole ligands: Synthesis, characterization and hydrogen storage capacities

Gördük

Yilmaz

Andaç

2019

Maced. J. Chem. Chem. Eng.

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Synthesis and structure of rhenium carbonyl complexes bearing a saccharinate ligand

Hasanuzzaman,

Sarker,

Al Mamun

et al. 2023

Zeitschrift anorg allge chemie

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Saccharin (sacH) reacts with [Re2(CO)8(NCMe)2] at room temperature to afford dinuclear [Re2(CO)8(μ‐H)(μ‐sac‐κN,O)] (1), which contains a bridging sac ligand coordinated to both rhenium centers using the nitrogen and ketonic oxygen atoms, and the mononuclear compounds [Re(CO)5(sac‐κN)] (2) and cis‐[Re(CO)4(NCMe)(sac‐κN)] (3), both of which contain a sac ligand bonded to rhenium using only the nitrogen atom. Complex 3 that contains an MeCN ligand reacts with tri(2‐furyl)phosphine (PFu3) at room temperature to yield cis‐[Re(CO)4(PFu3)(sac‐κN)] (4). The molecular structures of 1–4 have been established by X‐ray crystallography, and the bonding in compound 1 has been examined by electronic structure calculations.

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A novel zinc(II) complex containing square pyramidal, octahedral and tetrahedral geometries on the same polymeric chain constructed from pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole

Yilmaz

Andaç

2018

J Chem Sci

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Reactivity of [Re2(CO)8(MeCN)2] With 1-vinylimidazole: X-ray Structures of [Re2(CO)8{η 1-NC3H3N(CH=CH2)}2] and [ReCl2(CO)2{η 1-NC3H3N(CH=CH2)}2]

Cited by 10 publications

References 30 publications

Cu(II) and Cd(II) coordination polymers derived from pyrazine-2,3-dicarboxylato and 1-vinylimidazole ligands: Synthesis, characterization and hydrogen storage capacities

Cu(II) and Cd(II) coordination polymers derived from pyrazine-2,3-dicarboxylato and 1-vinylimidazole ligands: Synthesis, characterization and hydrogen storage capacities

Synthesis and structure of rhenium carbonyl complexes bearing a saccharinate ligand

A novel zinc(II) complex containing square pyramidal, octahedral and tetrahedral geometries on the same polymeric chain constructed from pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole

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