1993
DOI: 10.1006/jcat.1993.1280
|View full text |Cite
|
Sign up to set email alerts
|

Reactivity of Molybdovanadophosphoric Acids: Influence of the Presence of Vanadium in the Primary and Secondary Structure

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1

Citation Types

2
57
1
2

Year Published

2000
2000
2021
2021

Publication Types

Select...
8
1

Relationship

0
9

Authors

Journals

citations
Cited by 94 publications
(64 citation statements)
references
References 0 publications
2
57
1
2
Order By: Relevance
“…It is well known that vanadium-containing HPAs have a strong reduction potential (oxidizing power) [163]. 62 catalysts also showed volcanoshaped curves and exhibited the same trend with respect to vanadium substitution.…”
Section: Epoxidation Of Alkenes With H 2 Omentioning
confidence: 62%
“…It is well known that vanadium-containing HPAs have a strong reduction potential (oxidizing power) [163]. 62 catalysts also showed volcanoshaped curves and exhibited the same trend with respect to vanadium substitution.…”
Section: Epoxidation Of Alkenes With H 2 Omentioning
confidence: 62%
“…In all experiments performed, the synthesized catalyst showed more activity and selectivity in the diphenylsulfide oxidation to sulfoxide than the corresponding PMo, especially when vanadium was incorporated. The PMoV catalyst shows unique catalyst features for oxidation due to its bifunctional character, which arises because of the redox nature of Vanadium and the oxidation/acidic character of the molybdophosphoric acid [34]. As reported by Song et al [1], the metal substitution may be modifying the energy and composition of the lowest unoccupied molecular orbital (LUMO) and consequently its redox properties.…”
Section: Selective Oxidation Of Diphenylsulfidementioning
confidence: 94%
“…Vanadium-containing HPAs have been widely studied as catalysts for various oxidation reactions [26][27][28][29][30]. They showed excellent catalytic activities in several oxidation reactions such as oxidation of isobutyric acid [31], oxidation of methacrolein [32], oxidation of acrolein [33], and selective oxidation of alkane [34,35].…”
Section: Introductionmentioning
confidence: 99%