Reactivity of mercury(II) halides with the α-keto stabilized sulfonium ylides: Crystal structures of two new polymer and binuclear complexes and in vitro antibacterial study

A new Pd(II) complex of a sulfur ylide; Synthesis, X-ray characterization, theoretical study and catalytic activity toward the Suzuki–Miyaura reaction

“…However, activated aryl halides, such as aryl iodides and aryl bromides containing electronwithdrawing substituents, advance the reactions to give excellent yields (Table 9, entries [11][12][13][14][15][16]. …”

“…The complexation of sulfur ylides to various transition metals has been extensively studied [9,[11][12][13], however the synthesis, X-ray characterization, theoretical study and also application of a palladium complex of a sulfur ylide as a precursor in the Suzuki-Miyaura coupling reaction are the key advantages of this study. This paper includes the synthesis, spectroscopic and X-ray crystallographic characterization, theoretical study and application of new palladium(II) complex of an α-keto stabilized sulfur ylide in the Suzuki-Miyaura cross-coupling reaction.…”

Synthesis and Characterisation of Hg(II) Complexes Including Bidentate Phosphorus Ylides

“…Coordination of ligands towards Hg(II) has assumed importance since, in mercury's detoxification process, the initial Hg-C bond cleavage involves the increase in the coordination number around Hg. [26][27][28][29][30][31][32][33][34][35] In the present work, a series of Hg(II) complexes with ligand systems were prepared and their antibacterial activities were screened. 25 Here, we report the synthesis and characterisation of Hg(II) complexes with new asymmetrical phosphorus ylides derived from bis(diphenylphosphino) methane.…”

“…) and the complexes [(3) HgX 2 ] (X=Cl(11), Br(12), I(13)) and [(4) HgX 2 ] (X=Cl(14), Br(15), I (16)) were prepared based on the published methods [50][51][52]. calcd for C33 H 27 BrCl 2 HgOP 2 : C, 46.47; H, 3.19; found: C, 46.85; H, 3.08%. Yield 0.184 g (62%); m.p.…”

Synthesis, Spectroscopic and Antibacterial Studies of Silver(I) Complexes with Bidentate Phosphorus Ylides

“…31,32 Silver ions and silver-based compounds are known to be active at low concentrations and highly toxic to microorganisms. During the latter half of the century, particularly during the past decade, a number of different classes of antimicrobial compounds have been discovered.…”