Reaction of hexaalkyldisilanes with bromine and iodine

Bundel, Yu. G.; Bobrovskii, S. I.; Smirnov, V. V.; Новикова, И. А.; Sergeev, G. B.; Reutov, O. A.

doi:10.1007/bf00952488

Cited by 2 publications

(1 citation statement)

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“…Removal of the latter under reduced pressure gives pure dialkylbromoborane in 78–98% yield . Reaction of hexaalkyldisilanes with bromine was studied by Bundel et al They reported that a charge-transfer complex with bromine forms in the reaction. Bromination of the pseudosalasodine with bromine in benzene gave a mixture of C-23 epimeric cyclofurostans .…”

Section: Bromination Reactionsmentioning

confidence: 99%

Use of Bromine and Bromo-Organic Compounds in Organic Synthesis

2016

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Bromination is one of the most important transformations in organic synthesis and can be carried out using bromine and many other bromo compounds. Use of molecular bromine in organic synthesis is well-known. However, due to the hazardous nature of bromine, enormous growth has been witnessed in the past several decades for the development of solid bromine carriers. This review outlines the use of bromine and different bromo-organic compounds in organic synthesis. The applications of bromine, a total of 107 bromo-organic compounds, 11 other brominating agents, and a few natural bromine sources were incorporated. The scope of these reagents for various organic transformations such as bromination, cohalogenation, oxidation, cyclization, ring-opening reactions, substitution, rearrangement, hydrolysis, catalysis, etc. has been described briefly to highlight important aspects of the bromo-organic compounds in organic synthesis.

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Section: Bromination Reactionsmentioning

confidence: 99%