Reaction kinetics of cyclohexanone ammoximation over TS-1 catalyst in a microreactor

Kinetic Study of Reactions of Aniline and Benzoyl Chloride Using NH3 as Acid Absorbent in a Microstructured Chemical System

“…Microstructured chemical system has been widely used in the field of kinetic study in recent years, − for its enhanced mixing ability, high heat transfer efficiency, precise residence time control, less consumption of reactants, inherent safety, and so on. Taking advantages of the above characterizations, more accurate kinetic parameters are expected when using a microstructured chemical system. , Plenty of studies have been conducted successfully in a microstructured system, such as cyclohexanone ammoximation over TS-1 catalyst, fast exothermic premixing reactions, dehydrochlorination of dichloropropanol, and so on. Our previous kinetic study of the reactions between aniline and benzoyl chloride was also conducted in a microstructured chemical system .…”

“…Taking advantages of the above characterizations, more accurate kinetic parameters are expected when using a microstructured chemical system. 23,24 Plenty of studies have been conducted successfully in a microstructured system, such as cyclohexanone ammoximation over TS-1 catalyst, 25 fast exothermic premixing reactions, 23 dehydrochlorination of dichloropropanol, 26 and so on. Our previous kinetic study of the reactions between aniline and benzoyl chloride was also conducted in a microstructured chemical system.…”

Preparation of Keggin-type mono-lacunary phosphotungstic-ammonium salt and its catalytic performance in ammoximation of cyclohexanone

“…Although the ability of (NH 4 ) 5 (ZrO 2 )PW 11 O 39 to oxidize was stronger than (NH 4 ) 7 PW 11 O 39 , it had no simple corresponding relationship with the reaction results, which are correlated with the catalytic process in ammoximation system. Most researchers believe that the ammoximation of cyclohexanone was carried out according to a hydroxylamine mechanism [20,21], that is, the activated transition state formed with catalysts and hydrogen peroxide reacted with NH 3 to produce NH 2 OH, which played a key role in the reaction. Lacunary polyoxometalates substituted with transition metal or metal peroxide affected the formation of a hydrogen peroxide transition state because of the change in electronic structure and coordination environment.…”

Kinetics Study of Sulfuric Acid Alkylation of Isobutane and Butene Using a Microstructured Chemical System

“…Microstructured chemical systems show obvious advantages in kinetics measurement because of their good dispersion and the precise control of reaction time, as well as reaction conditions, especially for the rapid reaction of a heterogeneous system. − Plenty of kinetics studies were conducted in microstructured chemical systems, especially for a fast reaction controlled by mass transfer. − Zhang et al obtained the reaction kinetics of dehydrochlorination of dichloropropanol in a microstructured chemical system, showing distinct values for reaction mechanism understanding . Wang et al conducted experiments on the kinetics study of an aniline and benzoyl chloride reaction in a microstructured chemical system .…”