Rates of Water Oxidation in Ceric Perchlorate Solutions

Kolp, Don.; Thomas, Henry C.

doi:10.1021/ja01177a030

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Cited by 14 publications

(2 citation statements)

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“…(.17) carried out the oxidation of arsenite ion with ceri~m( IV) in HCl solution, and studied the effect of halide ions on the rate. Kal p and Thomas (18) attempted to determine the kinetics of oxidat·ion· of water by cerium(IV)perchlorate. This reaction ' !'…”

Section: +3mentioning

confidence: 99%

Oxidation of Chloride Ion by Cerium(iv)

Anderegg¹,

Duke²

1951

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Section: +3mentioning

confidence: 99%

Oxidation of Chloride Ion by Cerium(iv)

Anderegg¹,

Duke²

1951

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“…The eerie ions can be also reduced thermally (>30°C) [5]. Kiwi and Grätzel [6] succeeded to increase the oxygen yield by adding certain redox catalysts (Pt0 2 or Ir0 2 ).…”

Section: Introductionmentioning

confidence: 99%

Photocatalytic Splitting of Liquid Water by n-TiO₂ Suspension

Vonach

Getoff

1981

Zeitschrift Für Naturforschung A

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By illumination (A >300 nm) of a suspension of n-Ti02 (grain size 5^0.06 mm, 3 to 15 mg/ml) in aqueous acid solutions, containing 10 -3 mol • dm -3 Ce 4+ -ions an enhanced evolution of oxygen is observed. Its yield is dependent on the amount of TiC>2 in the suspension and on the temperature. Using n-TiC>2 suspended in diluted sulfuric acid, hydrogen and oxygen were produced in a ratio of about 2: 1. In both systems n-TiC>2 is acting as an efficient electron donor. For the explanation of the processes probable reaction mechanisms are proposed.

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Kinetics and mechanism of electron transfer reactions in aqueous solutions: Silver(I) catalyzed oxidation of aspartic acid by cerium (IV) in acid perchlorate medium

Sharma

Devra

Gupta

et al. 1995

Int J of Chemical Kinetics

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Silver(1) catalyzed oxidation of aspartic acid by cerium(1V) was studied in acid perchlorate medium. The stoichiometry of the reaction is represented by the eq. (i)Dimeric cerium(IV) species has been indicated and employed in calculations of monomeric cerium(IV) species concentrations. The reaction is second-order and uncatalyzed reaction also simultaneously occurs along with the silver(1) catalyzed reaction conforming to the rate law (ii)where k is an observed second-order rate constant. A probable reaction mechanism is suggested. 0 1995

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Rates of Water Oxidation in Ceric Perchlorate Solutions

Cited by 14 publications

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Oxidation of Chloride Ion by Cerium(iv)

Oxidation of Chloride Ion by Cerium(iv)

Photocatalytic Splitting of Liquid Water by n-TiO₂ Suspension

Kinetics and mechanism of electron transfer reactions in aqueous solutions: Silver(I) catalyzed oxidation of aspartic acid by cerium (IV) in acid perchlorate medium

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Rates of Water Oxidation in Ceric Perchlorate Solutions

Cited by 14 publications

References 0 publications

Oxidation of Chloride Ion by Cerium(iv)

Oxidation of Chloride Ion by Cerium(iv)

Photocatalytic Splitting of Liquid Water by n-TiO2 Suspension

Kinetics and mechanism of electron transfer reactions in aqueous solutions: Silver(I) catalyzed oxidation of aspartic acid by cerium (IV) in acid perchlorate medium

Contact Info

Product

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Photocatalytic Splitting of Liquid Water by n-TiO₂ Suspension