A new green synthesis method of CuInS₂ and CuInSe₂ nanoparticles and their integration into thin filmsAbstract A new preparation method for CuInS 2 and CuInSe 2 nanoparticles synthesis is described without using any organic solvent. Heating Cu, In, and S/Se precursors dissolved in water for 30 min in a microwave oven in the presence of mercapto-acetic acid leads to monodispersed chalcopyrite nanoparticles. No precipitation of these nanoparticles is observed after several months at room temperature. These new materials have been thoroughly characterized to confirm their compositions, sizes, and structure without any filtration. Transmission electron microscopy (TEM) confirmed particle sizes below 5 nm. Energy dispersive X-ray analysis (EDXA) confirmed the chemical composition of these samples. X-ray diffraction (XRD) showed a chalcopyritetype structure with crystallite size of about 2 nm.