Abstract:A microstructural analysis of silicon-on-insulator samples obtained by high dose oxygen ion implantation was performed by Raman scattering. The samples analyzed were obtained under different conditions thus leading to different concentrations of defects in the top Si layer. The samples were implanted with the surface covered with SiO 2 capping layers of different thicknesses. The spectra measured from the as-implanted samples were fitted to a correlation length model taking into account the possible presence o… Show more
“…This is interesting when studying nanocrystalline materials since average grain size is given by L. The main limit for this measurement is that phonon confinement only occurs for sizes in the nanometric range (L < 20 nm for Si). The changes in the bandshape and position of the Raman band related to phonon confinement has permitted the assessment of the average grain size and stress in nanocrystalline Si layers [8], as well as the density of defects in highly damaged Si films [9]. Figure 2 shows the spectra simulated for Si assuming spherical confinement and different values of the correlation length.…”
The potential of Raman microspectroscopy as a powerful tool in characterizing solids will be demonstrated here with several applications on semiconductors and thin films. The method not only permits the identification of different localized microscopic regions, with a high spatial resolution and with no sample preparation, but also provides several basic information on the microstructure of solids.
“…This is interesting when studying nanocrystalline materials since average grain size is given by L. The main limit for this measurement is that phonon confinement only occurs for sizes in the nanometric range (L < 20 nm for Si). The changes in the bandshape and position of the Raman band related to phonon confinement has permitted the assessment of the average grain size and stress in nanocrystalline Si layers [8], as well as the density of defects in highly damaged Si films [9]. Figure 2 shows the spectra simulated for Si assuming spherical confinement and different values of the correlation length.…”
The potential of Raman microspectroscopy as a powerful tool in characterizing solids will be demonstrated here with several applications on semiconductors and thin films. The method not only permits the identification of different localized microscopic regions, with a high spatial resolution and with no sample preparation, but also provides several basic information on the microstructure of solids.
“…However, the introduction of stress breaks the cubic symmetry and splits the triplet. The resultant stress can be estimated from the stress-induced wavenumber shift, Dv s [12,21,22], as…”
Section: Stress Estimation On Nanocrystalsmentioning
“…A red shift of the Raman peak is detected following Sb implantation and this increases with RTA at 600°C. A number of factors may contribute to this Si Raman peak shift, including stress, phonon confinement effects [7] and increased carrier concentration [8]. The broadening of the Si Raman peak and red-shift of the peak position is indicative of confinement effects resulting from partial amorphisation of the strained Si layer during ion implantation.…”
Section: Micro-raman Spectroscopymentioning
confidence: 99%
“…Thus the phonon's spatial confinement results in a broadening of the Raman scattering features reflecting the uncertainty in its energy and a red shift of the Raman peak position occurs with increasing spatial confinement, as lower-energy bulk-like phonons are incorporated into the wavefunction describing the nominally zone-centre confined phonon. The model used by Macia et al [7] to study silicon-on-insulator samples obtained by high dose oxygen ion implantation is adapted by introducing the parameter x 0 , which represents the stress-induced Raman line shift. Assuming a constant correlation length L in the scattering volume, the intensity of the first order Raman band of silicon is given by…”
Sheet resistance (R s ) reductions are presented for antimony doped layers in strained Si. We use microRaman spectroscopy to characterise the impact of a low energy (2 keV) Sb implantation into a thin strained Si layer on the crystalline quality and resultant stress in the strained Si. The use of 325 nm UV laser light enables us to extract information from the top~9 nm of the strained Si layer. Prior to implantation the Si layer is fully strained with a tensile stress value~1.41 GPa, in agreement with the calculated theoretical maximum on a strain relaxed buffer with 17% Ge content. There is a clear decrease in the intensity of the Si Raman signal following Sb implantation. The lattice damage and lattice recovery achieved by subsequent rapid thermal anneal (RTA) is quantified using the amplitude and full width at half maximum (FWHM) of the crystalline Si peak. The shift of the Raman Si peak is a key parameter in the interpretation of the spectra. The ion-implanted sample is studied in terms of a phonon coherence length confinement model. Carrier concentration effects are seen to play a role in the Raman shift following electrical activation of the Sb atoms by RTA.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.