Abstract:although the greater selectivity at higher temperatures would not necessarily be expected.General. The reactivities of the alkanes in telomerization with tetrafluoroethylene at 125 °C are all nearly the same.The trend of change in the linear alkanes is the same as that observed for photochlorination21 and for benzoyl peroxide catalyzed chlorination with 2,4,6-trichloro-N-chloroacetanilide.22 The reactivity of the cycloalkanes is less than that expected on the basis of the chlorination results with 2,4,6-trichl… Show more
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