This paper presents an overview of ammonium perchlorate (AP) based propellant ignitability. A CO 2 laser provided the radiant energy source. Neat AP ignition was performed on both production grade and high purity AP. The material was di©cult to ignite under the conditions. Five nonmetallized and sixteen metallized AP based formulations were used to examine the e¨ects of particle size, binder type, additives, and coarse-to-¦ne ratio (C/F) on propellant ignitability.