Fate and distribution of pyrimethanil, metalaxyl, dichlofluanid and penconazol fungicides from treated grapes intended for winemaking. Food Additives and Contaminants, 2009, 26 (02) were in contact with the fungicide solutions. Residues were mainly found in skins, with 31 percentages in skins ranged from 66.3 to 90.3 % of total residues. In pulp, these values 32 were ranged from 3.5 to 31.0 %. The overall methodology was applied to the 33 determination of pyrimethanil in Tempranillo grapes treated with the recommended 34 doses, respecting the safety period. Pyrimethanil residues found in treated grapes were 35 higher in the skin. In grapes collected within the safety period (21 days), the levels 36 found for fungicide residues were below Maximum Residues Levels. 37 38