Quercetin-Zirconium: A Green and Highly Efficient Catalyst for the Meerwein–Ponndorf–Verley Reduction of Furfural

Peng, Qingrui; Wang, Haijun; Xia, Yongmei

doi:10.1007/s10562-022-04009-z

Cited by 4 publications

(2 citation statements)

References 50 publications

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“…For achieving comparable furfural conversion and furfuryl alcohol yield, in comparison to the reactions at 120 °C, enhancing the reaction temperature can decrease the reaction time (entries 4–6); at a lower temperature of 100 °C, more reaction time is needed (entry 1). Table lists the furfural conversion and furfuryl alcohol yield over various Zr-based catalysts. − ,,− Under identical reaction conditions (temperature and amount of furfural), PDBMA&Zr exhibited higher values of TOF than many Zr-based catalysts.…”

Section: Resultsmentioning

confidence: 99%

Poly(divinylbenzene-maleic acid) Hollow Nanospheres Coordinated with Zirconium: An Effective Catalyst for the Catalytic Transfer Hydrogenation of Furfural to Furfuryl Alcohol

Sun,

Jiao,

2024

Ind. Eng. Chem. Res.

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Poly(divinylbenzene-maleic acid) (PDBMA) hollow nanospheres with a high content of carboxylic acid groups were prepared. Through the confinement coordination of Zr 4+ ions with the carboxylic acid groups of the backbone of PDBMA, the hybrid PDBMA&Zr hollow nanospheres were synthesized. PDBMA&Zr possesses a high content of coordinatively unsaturated zirconium sites (Zr cus ). PDBMA&Zr exhibited significantly high catalytic efficiency for the catalytic transfer hydrogenation of furfural to furfuryl alcohol. Two aspects contribute to high catalytic efficiency: the high content of coordinatively unsaturated zirconium sites and the high accessibility of zirconium sites by the reactant furfural. The mechanism for the catalytic transfer hydrogenation reaction by PDBMA&Zr has been investigated.

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Section: Resultsmentioning

confidence: 99%

Poly(divinylbenzene-maleic acid) Hollow Nanospheres Coordinated with Zirconium: An Effective Catalyst for the Catalytic Transfer Hydrogenation of Furfural to Furfuryl Alcohol

Sun,

Jiao,

2024

Ind. Eng. Chem. Res.

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“…It has been reported that MPV reduction reaction can be efficiently catalyzed by diverse catalysts, such as metal alkoxides and complexes, hydrotalcites, metal oxides or hydroxides, various zeolites, and so forth. Among the catalysts, Zr‐based catalysts including ZrO 2 , 12 zirconium alkoxides, 11 Zr‐containing zeolites, 13 Zr (OH) 4 , 14 and quercetin‐Zr 15 are the commonly used ones. However, there are still some drawbacks for Zr‐based catalysts, such as deactivation and the need of harsh reaction conditions 16 …”

Section: Introductionmentioning

confidence: 99%

Organodiphosphonate Zr‐MOF: A highly efficient catalyst for Meerwein–Ponndorf–Verley reduction of furfural

Xia

Qin

et al. 2023

Asia-Pacific J Chem Eng

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Tetraethyl p‐xylenediphosphate is used as the organic ligand to prepare the organodiphosphonate Zr‐based metal organic frameworks (ZrP‐MOF). The physicochemical characterizations of ZrP‐MOF under different hydrothermal and calcination conditions were performed by various analytical techniques. ZrP‐MOF was then employed as a catalyst for the catalytic transfer hydrogenation of furfural with alcohol as the hydrogen donor, and the preparation parameters and catalytic properties of ZrP‐MOF were investigated. Compared with fresh ZrP‐MOF, the furfural conversion of ZrP‐MOF calcined at 825 K increased from 43.5% to 95.1%. Calcination can significantly increase the Lewis/Brønsted acid ratio and enlarge the pore structure of ZrP‐MOF, which promote the furfural catalytic transfer hydrogenation reaction over Zr‐O based on the Meerwein–Ponndorf–Verley reduction.

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Highly selective transfer hydrogenation of biomass-derived furfural to furfuryl alcohol over a zirconium-melamine coordination catalyst without Brønsted acid sites

Hu,

Chen,

et al. 2023

Chemical Engineering Journal

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Quercetin-Zirconium: A Green and Highly Efficient Catalyst for the Meerwein–Ponndorf–Verley Reduction of Furfural

Cited by 4 publications

References 50 publications

Poly(divinylbenzene-maleic acid) Hollow Nanospheres Coordinated with Zirconium: An Effective Catalyst for the Catalytic Transfer Hydrogenation of Furfural to Furfuryl Alcohol

Poly(divinylbenzene-maleic acid) Hollow Nanospheres Coordinated with Zirconium: An Effective Catalyst for the Catalytic Transfer Hydrogenation of Furfural to Furfuryl Alcohol

Organodiphosphonate Zr‐MOF: A highly efficient catalyst for Meerwein–Ponndorf–Verley reduction of furfural

Highly selective transfer hydrogenation of biomass-derived furfural to furfuryl alcohol over a zirconium-melamine coordination catalyst without Brønsted acid sites

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