Quantitative analysis of Fe-based samples using ultraviolet nanosecond and femtosecond laser ablation-ICP-MS

Možná, Veronika; Pisonero, Jorge; Holá, Markéta; Kanický, Viktor; Günther, Detlef

doi:10.1039/b606988f

Cited by 74 publications

(35 citation statements)

References 27 publications

(34 reference statements)

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“…In order to restrain these effects, the laser pulse duration needs to be shorter than the thermal relaxation time of a few hundred femtoseconds [9]. Možná et al [10] compared the performance of ns-UV-LA-ICPMS and fs-UV-LA-ICPMS for Fe-based samples and showed that fs-LA provides more accurate results. Bian et al [11] reported the successful non-matrix matched quantification of Zn and Cu in brass, aluminum and silicate glass.…”

Section: Introductionmentioning

confidence: 99%

Phenomenological studies on structure and elemental composition of nanosecond and femtosecond laser-generated aerosols with implications on laser ablation inductively coupled plasma mass spectrometry

Glaus

Kaegi

Krumeich

et al. 2010

Spectrochimica Acta Part B: Atomic Spectroscopy

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Section: Introductionmentioning

confidence: 99%

Phenomenological studies on structure and elemental composition of nanosecond and femtosecond laser-generated aerosols with implications on laser ablation inductively coupled plasma mass spectrometry

Glaus

Kaegi

Krumeich

et al. 2010

Spectrochimica Acta Part B: Atomic Spectroscopy

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“…Možná et al . () compared the performance of ns‐UV‐LA‐ICP‐MS and fs‐UV‐LA‐ICP‐MS for Fe‐based samples and showed that the fs‐LA provided more accurate results using non‐matrix‐matched calibration procedures. Wiltsche and Günther () investigated the capabilities of near infrared (NIR) fs‐LA‐ICP‐MS for the quantification of major, minor and trace elements in unalloyed, alloyed and highly alloyed steels and super alloys.…”

mentioning

confidence: 99%

Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

Günther

et al. 2016

Geostandard Geoanalytic Res

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Ilmenite (FeTiO3) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised 57Fe and 49Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm−2 and fs‐LA‐ICP‐MS.

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“…Poitrasson et al (2003) compared analytical precision, repeatability and accuracy of nanosecond versus femtosecond LA-ICP-MS (fs-LA-ICP-MS) determinations using reference glasses and natural minerals. Horn et al (2006) performed in situ Fe-isotope ratio determinations in minerals using ultraviolet (UV) femtosecond LA-MC-ICP-MS. González et al (2006) worked on repeatability of glass microanalyses and Mozná et al (2006) performed quantitative analysis of Fe-rich samples using UV femtosecond and nanosecond LA-ICP-MS (ns-LA-ICP-MS). Freydier et al (2008) studied the influence of pulse duration and wavelength on the internal precision, reproducibility and accuracy of LA quadrupole ICP-MS measurements.…”

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confidence: 99%

In Situ Multi‐Element Analysis of the Mount Pinatubo Quartz‐Hosted Melt Inclusions by NIR Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Mass Spectrometry

Borisova

Freydier

Polvé

et al. 2008

Geostandard Geoanalytic Res

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Microscopic melt inclusions found in magmatic minerals are undoubtedly one of the most important sources of information on the chemical composition of melts. This paper reports on the successful application of near‐infrared (NIR) femtosecond laser ablation (LA) ‐ inductively coupled plasma‐mass spectrometry to in situ determination of incompatible trace elements (Li, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Ta, Th, U) and ore metals (As, Mo, Pb) in individual melt inclusions hosted in quartz from the Mount Pinatubo dacites, Philippines. The determined elements cover a concentration range of five orders of magnitude. Femtosecond LA‐ICP‐MS analyses of twenty‐eight individual melt inclusions demonstrate the efficiency of the microanalytical technique and suggests a spectacular homogeneity of the entrapped melt, at least with respect to the following incompatible trace elements: Rb, Sr, Nb, Cs, Ba, La, Ce, Pr, Nd, Pb, Th. The analytical precision (1s) for Na, Ca, Rb, Sr, Y, Nb, Ba and LREE ranged from 3 to 20%. Comparison of trace element concentrations in Mt. Pinatubo melt inclusions determined by femtosecond LA‐ICP‐MS with those of melt inclusions previously analysed by secondary ion mass spectrometry analysis (SIMS) and those of matrix glasses previously determined by nanosecond LA‐ICP‐MS showed an agreement typically within 30–40%. The homogeneity of trace element concentrations of the Mt. Pinatubo melt inclusions and the matrix glasses is consistent with the melt inclusion origin as homogeneous rhyolitic melt that was trapped in quartz phenocrysts at the final crystallisation stages of the host adakite (dacite) magma.

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Quantitative analysis of Fe-based samples using ultraviolet nanosecond and femtosecond laser ablation-ICP-MS

Cited by 74 publications

References 27 publications

Phenomenological studies on structure and elemental composition of nanosecond and femtosecond laser-generated aerosols with implications on laser ablation inductively coupled plasma mass spectrometry

Phenomenological studies on structure and elemental composition of nanosecond and femtosecond laser-generated aerosols with implications on laser ablation inductively coupled plasma mass spectrometry

Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

In Situ Multi‐Element Analysis of the Mount Pinatubo Quartz‐Hosted Melt Inclusions by NIR Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Mass Spectrometry

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