Pyrolysis characteristics of low-rank coal in a low-nitrogen pyrolysis atmosphere and properties of the prepared chars

Ma, Cheng; Zhao, Yue; Lang, Tingting; Zou, Chong; Zhao, Junxue; Miao, Zongcheng

doi:10.1016/j.energy.2023.127524

Cited by 9 publications

(1 citation statement)

References 35 publications

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“…The carbon conversion x and reactivity index R 0.5 are calculated using the (6) [47] and (7) [48], respectively.…”

Section: Calculation and Analysis Methodsmentioning

confidence: 99%

Experimental Study on the Thermal Reduction of CO2 by Activated Solid Carbon-Based Fuels

Zhang,

Liang,

Zhu

et al. 2024

Energies

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For achieving CO2 thermal reduction, a technology combining solid carbon activation and high-temperature CO2 reduction was proposed, named as activated-reduction technology. In this study, this technology is realized by using a circulating fluidized bed and downdraft reactor. Reduced agent parameters (O2/C and CO2 concentration) greatly affect the reduction effect of CO2. In addition, the effect of the activation process on different carbon-based materials can help to broaden the range of carbon-based materials used for CO2 reduction, which is also an important issue. The following three points have been studied through experiments: (1) the influence of the characteristics of the reduced agent (CO2 concentration and O2/C) on CO2 reduction; (2) the performance of different chars in CO2 reduction; and (3) the activation effect of solid carbon. The activation process can develop the pore structure of coal gasification char and transform it into activated char with higher reactivity. The CO concentration in the tail gas is a crucial factor limiting the effectiveness of CO2 reduction, with an experimentally determined upper limit of around 55% at 1200 °C. If CO concentration is far from the upper limit, temperature becomes the significant influencing factor. When the reduced agent O2/C is 0.18, the highest net CO2 reduction of 0.021 Nm3/kg is achieved at 60% CO2 concentration. When the reduced agent CO2 concentration is 50%, the highest net CO2 reduction of 0.065 Nm3/kg is achieved at 0.22 O2/C. Compared with CPGC, YHGC has higher reactivity and is more suitable for CO2 reduction. The activation process helps to reduce the differences between raw materials.

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“…The carbon conversion x and reactivity index R 0.5 are calculated using the (6) [47] and (7) [48], respectively.…”

Section: Calculation and Analysis Methodsmentioning

confidence: 99%

Experimental Study on the Thermal Reduction of CO2 by Activated Solid Carbon-Based Fuels

Zhang,

Liang,

Zhu

et al. 2024

Energies

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Free-radical behaviors of co-pyrolysis of low-rank coal and different solid hydrogen-rich donors: A critical review

Wu,

Guan,

et al. 2023

Chemical Engineering Journal

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Pyrolysis characteristics and product distribution of low-rank coal with heat-carrying particles adopting TG-FTIR and a novel self-mixing down tube reactor

Gao,

Sun,

Tian

2024

Case Studies in Thermal Engineering

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Pyrolysis characteristics of low-rank coal in a low-nitrogen pyrolysis atmosphere and properties of the prepared chars

Cited by 9 publications

References 35 publications

Experimental Study on the Thermal Reduction of CO2 by Activated Solid Carbon-Based Fuels

Experimental Study on the Thermal Reduction of CO2 by Activated Solid Carbon-Based Fuels

Free-radical behaviors of co-pyrolysis of low-rank coal and different solid hydrogen-rich donors: A critical review

Pyrolysis characteristics and product distribution of low-rank coal with heat-carrying particles adopting TG-FTIR and a novel self-mixing down tube reactor

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