PVT Relationships of Binary Mixtures of Indole with 2-Methylnaphthalene and Biphenyl at 333.15 K and Pressures up to 270 MPa

Abstract

PVT relationships of two binary mixtures of indole with 2-methylnaphthalene and with biphenyl have been measured at 333.15 K and at pressures up to 270 MPa or up to near the freezing pressure of each mixture. The compositions in mole fraction of indole were set to be 0.2500, 0.5000, and 0.7500 for both systems. PVT relationships of indole (at 343.15 K and 353.15 K), 2-methylnaphthane (at 333.15 K and 343.15 K), and biphenyl (at 353.15 K and 363.15 K) under pressure and those for the binary mixtures at 0.1 MPa in the temperature range from 293.15 K to 363.15 K were also measured. PVT data were analyzed with the use of the Tait equation and Carnahan-Starling-van der Waals (CS-vdW) equation. It was found that both the equations can be used to represent the experimental PVT relationships for the pure compounds and the binary mixtures with an average absolute deviations of 0.04 % for the Tait equation and 0.29 % for the CS-vdW equation. As for mixture density calculations with the CS-vdW equation, the effect of mixing rules was investigated.

Liquid Densities of Xylene Isomers and 2-Methylnaphthalene at Temperatures to 523 K and Pressures to 265 MPa: Experimental Determination and Equation of State Modeling

“…The largest δ, 0.30%, is smaller than the estimated expanded uncertainty ( k = 2), ±0.75%, of the experimental data. Calculated values of ρ 0 agree with ambient-pressure density data reported in the literature − to within ±0.10%.…”

“…Percent deviation for 2-methylnaphthalene densities obtained with the Tait equation fit to data obtained in this study, ρ i ,corr , and literature data, ρ i ,lit , of Ebina et al (■).…”

CHAPTER 15. Volumetric Properties and Thermodynamic Response Functions of Liquids and Liquid Mixtures

“…Some authors [45][46][47][48][49] have taken the same parameter C for all the compositions. In this case, obviously the reference pressure density is different for each composition and temperature, r 0 (x 1 , T).…”