1988
DOI: 10.1002/kin.550201106
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Pulse radiolysis study of formation of poly(4‐vinylbiphenyl) anions in 2‐methyltetrahydrofuran solution at 100–120 K

Abstract: The reactions of poly(4-vinylbiphenylj (denoted as PVB) polymers and biphenyl molecules with solvated electrons in the 2-methyltetrahydrofuran(MTHFj solvent have been studied at 100-120 K by electron-pulse radiolysis. The formation of PVB polymer anions as well as biphenyl anions was observed by the electron-pulse irradiation of the MTHF-PVB(or biphenyl) solution. The anions are formed by two processes; a rapid formation during the pulse irradiation (<20 ns) and a slow formation after the pulse irradiation. Th… Show more

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Cited by 4 publications
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“…The complex kinetics of such reactions are not only relevant for the particular problem that is addressed in this work but are of general importance . Examples of diffusion-limited reactions of the type discussed here include fluorescence quenching, , reaction of small reactive species with polymers, and the binding of a small substrate to the catalytic site of an enzyme and numerical methods.
1 Molecular structure of MEH−PPV.
…”
Section: Introductionmentioning
confidence: 99%
“…The complex kinetics of such reactions are not only relevant for the particular problem that is addressed in this work but are of general importance . Examples of diffusion-limited reactions of the type discussed here include fluorescence quenching, , reaction of small reactive species with polymers, and the binding of a small substrate to the catalytic site of an enzyme and numerical methods.
1 Molecular structure of MEH−PPV.
…”
Section: Introductionmentioning
confidence: 99%