Pt supported micro-mesoporous catalysts: synthesis, characterization and catalytic evaluation in n-heptane isomerization

Iron‐Catalyzed Positional and Geometrical Isomerization of Alkenes

“…For decades, precious metal‐based catalysts such as Ru, [29–41] Rh, [42–48] Pd, [49–57] Ir, [58–71] Pt, [72–74] and Mo, [75,76] have been at the forehead of metal‐catalyzed alkene isomerization to address the challenges and selectivity issues and to enrich the reaction applications pertaining to scope and synthetic usefulness. However, the low abundance, high cost and high toxicity of these metals have stimulated the exploration of earth‐abundant first‐row late transition metals as sustainable alternatives that could additionally feature distinct and complementary reactivity behaviors thanks to a large set of redox and spin states [77] .…”

“…For decades, precious metal-based catalysts such as Ru, [29][30][31][32][33][34][35][36][37][38][39][40][41] Rh, [42][43][44][45][46][47][48] Pd, [49][50][51][52][53][54][55][56][57] Ir, [58][59][60][61][62][63][64][65][66][67][68][69][70][71] Pt, [72][73][74] and Mo, [75,76] have been at the forehead of metal-catalyzed alkene isomerization to address the challenges and selectivity issues and to enrich the reaction applications pertaining to scope and synthetic usefulness. However, the low abundance, high cost and high toxicity of these metals have stimulated the exploration of earth-abundant firstrow late transition metals as sustainable a...…”