2022
DOI: 10.1039/d2cp00616b
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Proton-phosphorous connectivities revealed by high-resolution proton-detected solid-state NMR

Abstract: Proton-detected solid-state NMR enables atomic-level insight in solid-state reactions, for instance in heterogeneous catalysis, which is fundamental for deciphering chemical reaction mechanisms. We herein introduce a phosphorus-31 radiofrequency channel in...

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Cited by 6 publications
(1 citation statement)
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References 97 publications
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“…The 19 F nuclei have also been used as spy spin for the indirect detection of 13 C nuclei using DCP scheme in the case of mesoporous silica functionalized with fluorinated organic moieties 202 . More recently, DCP sequence has been employed for the indirect detection via protons of low-γ spin-1/2 isotopes, including 89 Y, 103 Rh and 183 W, in inorganic and hybrid materials 217 as well as 31 P nuclei in phosphane/borane 218 . The sensitivity of DCP experiment with 1 H detection has also been enhanced using DNP 200 .…”
Section: Between Spin-1/2 Isotopesmentioning
confidence: 99%
“…The 19 F nuclei have also been used as spy spin for the indirect detection of 13 C nuclei using DCP scheme in the case of mesoporous silica functionalized with fluorinated organic moieties 202 . More recently, DCP sequence has been employed for the indirect detection via protons of low-γ spin-1/2 isotopes, including 89 Y, 103 Rh and 183 W, in inorganic and hybrid materials 217 as well as 31 P nuclei in phosphane/borane 218 . The sensitivity of DCP experiment with 1 H detection has also been enhanced using DNP 200 .…”
Section: Between Spin-1/2 Isotopesmentioning
confidence: 99%