“…Their versatility is due to the composition of heteropolymers which offers numerous opportunities of interactions and cross-linking reactions inducing original gas barrier properties and selectivity. Strategies to improve barrier and mechanical properties of WG-based films consist of modifying the polymer network by applying thermal treatments (Ali, Ghorpade, & Hanna, 1997;Micard, Belamri, Morel, & Guilbert, 2000), by mixing wheat gluten with hydrophobic biodegradable polymers such as polycaprolactone (John, Tang, & Bhattacharya, 1998) or by incorporating nanofillers such as Montmorillonite (Alexandre & Dubois, 2000;Tunc, Angellier et al, 2007). In the last few years, many studies have been devoted to hybrid organic-inorganic systems and, in particular, to those in which layered silicates were dispersed at a nanometric scale in a polymer matrix (Dean & Yu, 2005;Rhim, 2005;Sinha Ray, 2010;Wang et al, 2005;Yu, Dean, & Li, 2006).…”