Advanced Materials in Catalysis 1977
DOI: 10.1016/b978-0-12-147450-8.50009-5
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Properties of Carbides, Nitrides, and Borides: Implications for Catalysis

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Cited by 18 publications
(4 citation statements)
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“…Iron-group metals (Co, Fe, Ni) and Mo form interstitial borides, carbides, nitrides and sulfides, as well as mixed compounds such as carbonitrides and oxycarbides (Levy, 1977), some having unique activityselectivity properties in FTS (Anderson, 1984;Bartholomew, 1991). The most important of these interstitial compounds are the carbides and oxycarbides of Fe, formed during typical FTS pretreatment and reaction conditions, which produce a typical product slate.…”
Section: Co and Fe Catalysts: Catalyst Activity-structure Relationshimentioning
confidence: 99%
“…Iron-group metals (Co, Fe, Ni) and Mo form interstitial borides, carbides, nitrides and sulfides, as well as mixed compounds such as carbonitrides and oxycarbides (Levy, 1977), some having unique activityselectivity properties in FTS (Anderson, 1984;Bartholomew, 1991). The most important of these interstitial compounds are the carbides and oxycarbides of Fe, formed during typical FTS pretreatment and reaction conditions, which produce a typical product slate.…”
Section: Co and Fe Catalysts: Catalyst Activity-structure Relationshimentioning
confidence: 99%
“…Carbides and nitrides of Zr and Hf were previously reviewed together with other transition metals in monographs by Goldschmidt [20] and Storms in 1967 [21], Toth in 1971 [22], Pierson in 1996 [23], and in a collection of papers edited by Freer in 1990 [24], Samsonov in 1995 [25], Oyama in 1996 [26], Gogotsi and Andrievski in 1999 [27]. Catalytic properties were reviewed by Levy in 1977 [28] and by Ham and Lee in 2009 [29]. Monograph by Turchanins 1991 [30] presented in details 20-year of original experimental work on the thermodynamics of refractory carbides and carbonitrides, some of which were previously published in English [31,32,33,34], but the monograph is only available in Russian.…”
Section: Introductionmentioning
confidence: 99%
“…The possibility of metal borides for HDS upgrading of oil has been suggested in the literature; their refractory nature, reported resistance to sulfur poisoning, and known desulfurization ability in organic synthesis make metal borides potentially desirable catalysts. The few HDS experiments reported with metal borides, however, do not provide quantitative activity measurements, analysis of the active HDS phase, or thorough characterization of both the new and used catalyst.…”
Section: Introductionmentioning
confidence: 99%