The localized interaction between
metallic nanostructures and surrounding
fluorescent molecules can influence the emission characteristics of
the molecule. With this hindsight, herein, by employing a Fourier
optical fluorescence microscope, we experimentally show how fluorescence
emission from molecules in the vicinity of a chemically prepared silver
nanowire-dimer-junction can be directed in one or two channels. Measured
forward-to-backward ratio of the fluorescence emission in a single
channel was as high as 4.3 dB, and the observed polar and azimuthal
angular spread was as narrow as 15° and 60°, respectively.
Interestingly, the angle between the two emission channels mimicked
the angle between the nanowires, thus, highlighting the prospect of
geometrical control of the emitted light. These observations were
further corroborated by three-dimensional finite-difference time-domain
simulations. The presented results will have implications in momentum-space
engineering of molecular fluorescence emission and can be extrapolated
to single-emitter studies.