Production of Methanation Catalysts

Bridger, G. W.; Woodward, C. F.

doi:10.1016/s0167-2991(08)63962-2

Cited by 2 publications

(1 citation statement)

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“…With regard to this, the industrial methanation catalysts are essentially nickel metal at a large scale of concentrations (25-77 wt%) due to their high activity, selectivity toward methane formation in preference to other hydrocarbons, high thermal stability, and relatively low cost [28][29][30][31].…”

Section: Introductionmentioning

confidence: 99%

Ni–Al layered double hydroxides as catalyst precursors for CO2 removal by methanation

Gabrovska

Edreva-Kardjieva

Crışan

et al. 2011

Reac Kinet Mech Cat

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The effect of nickel content on the structure and activity of co-precipitated Ni-Al layered double hydroxides (LDHs) as catalyst precursors for CO 2 removal by methanation was studied by variation of the Ni 2? /Al 3? molar ratio (Ni 2? /Al 3? = 3.0, 1.5 and 0.5), and of the reduction and reaction temperatures as well as of the space velocities. Powder X-ray diffraction (PXRD), H 2 chemisorption, and temperature programmed reduction (TPR) techniques were applied for physicochemical characterization of the samples. It was specified that the nanoscaled dimensions of the as-synthesized samples also generate nano-metrical metallic nickel particles (PXRD). The existence of readily and hardly reducible Ni 2? -O species in the studied samples (TPR), affects catalytic performance. The studied catalysts hydrogenate CO 2 effectively to residual concentrations of the latter in the range of 0-10 ppm at reaction temperatures from 400 to 220°C and space velocities between 22,000 and 3000 h -1 . The variation of the CO 2 methanation activity with the changes of space velocities depends on the nickel content, and reduction and reaction temperatures. After reduction at 400 and 450°C, a sample of Ni 2? /Al 3? = 3.0 has demonstrated the highest conversion degree at all the reaction temperatures and space velocities, while a catalyst of Ni 2? /Al 3? = 0.5 dominated in the methanation activity after reduction within 530-600°C. The Ni 2? /Al 3? = 1.5

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Section: Introductionmentioning

confidence: 99%