2000
DOI: 10.1557/jmr.2000.0262
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Processing and Characterization of High-conductance Bismuth Wire Array Composites

Abstract: We fabricated Bi nanowire array composites with wire diameters from 30 to 200 nm by high-pressure injection (HPI) of Bi melt into porous anodic alumina templates. The composites were dense, with Bi volume fraction in excess of 50%. The parallel Bi nanowires, whose length appeared to be limited only by the thickness of the host template (up to 55 m), terminated at both sides of the composite in the Bi bulk. The individual Bi nanowire crystal structure was rhombohedral, with the same lattice parameters as that o… Show more

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Cited by 46 publications
(32 citation statements)
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“…The arrays of Bi nanowires employed here are synthesized by injecting 11 molten Bi into anodic alumina templates. The hexagonal array of nanochannels in the templates is selfassembled by the anodization of Al.…”
mentioning
confidence: 99%
“…The arrays of Bi nanowires employed here are synthesized by injecting 11 molten Bi into anodic alumina templates. The hexagonal array of nanochannels in the templates is selfassembled by the anodization of Al.…”
mentioning
confidence: 99%
“…[7, 81 Many papers present excellent experimental results documenting conditions at which time anodization forms ordered pores and those at which the pores are irregular and not ordered. [9,10,11] However, to our knowledge, no complete theory exists to predict the optimal acid type, concentration, and temperature that should be used to obtain well-ordered arrays with a uniform pore diameter for a given anodization voltage and corresponding pore diameter. Therefore, whenever the desired pore size has not yet been well studied, many attempts of trial and error are required to establish the recipe for well-ordered In our samples, in addition to the increase in current at breakdown, sizzling occurred at the air/acid interface where the aluminum was exposed to air.…”
Section: Fabrication and Experimental Detailsmentioning
confidence: 99%
“…Two types of templates were generally used, "track-etch" polymeric membrane and porous anodic alumina membrane (AAM). Nanoscopic cylinders can be embedded in templates by pressure injection, sol-gel chemistry, chemical deposition and vapor-phase technique [10][11][12][13][14][15]. A variety of nanowires and nanotubes has been prepared, including metals, semiconductors, polymers, carbon, and many other materials [16][17][18][19][20].…”
Section: Introductionmentioning
confidence: 99%