Processes affecting geochemistry and contaminant movement in the middle Claiborne aquifer of the Mississippi embayment aquifer system

Abstract

Groundwater chemistry and tracer-based age data were used to assess contaminant movement and geochemical processes in the middle Claiborne aquifer (MCA) of the Mississippi embayment aquifer system. Water samples were collected from 30 drinking-water wells (mostly domestic and public supply) and analyzed for nutrients, major ions, pesticides, volatile organic compounds (VOCs), and transient age tracers (chlorofluorocarbons, tritium and helium-3, and sulfur hexafluoride). Redox conditions are highly variable throughout the MCA. However, mostly oxic groundwater with low dissolved solids is more vulnerable to nitrate contamination in the outcrop areas east of the Mississippi River in Mississippi and west Tennessee than in mostly anoxic groundwater in downgradient areas in western parts of the study area. Groundwater in the outcrop area was relatively young (apparent age of less than 40 years) with significantly (p \ 0.05) higher dissolved oxygen and nitrate-N concentrations and higher detections of pesticides and VOCs compared to water samples from wells in downgradient areas. Oxygen reduction and denitrification rates were low compared to other aquifers in the United States (zero order rate constants for oxygen reduction and denitrification were 4.7 and 5-10 lmol/L/year, respectively). Elevated concentrations of nitrate-N, and detections of pesticides and VOCs in some deep public supply wells ([50 m depth) indicated contaminant movement from shallow parts of the aquifer into deeper oxic zones. Given the persistence of nitrate in young oxic groundwater that was recharged several decades ago, and the lack of a confining unit, the downward movement of young contaminated water may result in higher nitrate concentrations over time in deeper parts of the aquifer containing older oxic water.

The quality of our Nation's waters: water quality in the Mississippi embayment-Texas coastal uplands aquifer system and Mississippi River Valley alluvial aquifer, south-central United States, 1994-2008

“…Where the confining layer is thin or absent, shallow groundwater can move downward into the middle Claiborne aquifer. (9,27,37) Pesticides and VOCs have been detected in the middle Claiborne aquifer in only a few locations in the Memphis area, (9,38,39,40) but these contaminants were detected relatively frequently in samples of shallow groundwater (chapter 6). Changes in specific conductance of groundwater over time indicate areas where the middle Claiborne aquifer is vulnerable to leakage from the overlying shallow aquifer ( fig.…”