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Water wells (n = 116) overlying the Eagle Ford, Fayetteville, and Haynesville Shale hydrocarbon production areas were sampled for chemical, isotopic, and groundwater-age tracers to investigate the occurrence and sources of selected hydrocarbons in groundwater. Methane isotopes and hydrocarbon gas compositions indicate most of the methane in the wells was biogenic and produced by the CO reduction pathway, not from thermogenic shale gas. Two samples contained methane from the fermentation pathway that could be associated with hydrocarbon degradation based on their co-occurrence with hydrocarbons such as ethylbenzene and butane. Benzene was detected at low concentrations (<0.15 μg/L), but relatively high frequencies (2.4-13.3% of samples), in the study areas. Eight of nine samples containing benzene had groundwater ages >2500 years, indicating the benzene was from subsurface sources such as natural hydrocarbon migration or leaking hydrocarbon wells. One sample contained benzene that could be from a surface release associated with hydrocarbon production activities based on its age (10 ± 2.4 years) and proximity to hydrocarbon wells. Groundwater travel times inferred from the age-data indicate decades or longer may be needed to fully assess the effects of potential subsurface and surface releases of hydrocarbons on the wells.

[1] Using heat as a tracer, quantitative estimates of streambed fluxes and the critical stage for flow reversal were calculated for high-flow events that occurred on the Bogue Phalia (a tributary of the Mississippi River) following the 2005 Hurricanes Katrina and Rita. In June 2005, piezometers were installed in the Bogue Phalia upstream from the stream gage near Leland, Mississippi, to monitor temperature. Even with the hurricanes, precipitation in the Bogue Phalia Basin for the months of June to October 2005 was below normal, and consequently, streamflow was below the long-term average. Temperature profiles from the piezometers indicate that the Bogue Phalia was a gaining stream during most of this time, but relatively static streambed temperatures suggested long-term data was warranted for heat-based estimates of flux. However, the hurricanes caused a pair of sharp rises in stream stage over short periods of time, increasing the potential for rapid heat-based modeling and for identification of the critical stage for flow reversal into the streambed. Heat-based modeling fits of simulated-to-measured sediment temperatures show that once a critical stage was surpassed, flow direction reversed into the streambed. Results of this study demonstrate the ability to constrain estimates of streambed water flux and the critical stage of flow reversal, with little available groundwater head data, by using heat as a tracer during extreme stage events.

Map showing study area and wells sampled as part of the Georgia-Florida urban land-use study network (gafllusrc1) near Tampa, Florida, for the U.S. Geological Survey National Water-Quality Assessment Project, July through November 2012 ......18 12. Map showing study area and wells sampled as part of the Nevada Basin and Range urban land use study network (nvbrlusrc1) near Reno and Carson City, Nevada, for the U.

The Mississippi Delta, a portion of the Mississippi Alluvial Plain (MAP) located in northwest Mississippi (USA), is an area dense with industrial-level agriculture sustained by groundwater-dependent irrigation supplied by the Mississippi River Valley alluvial aquifer. Observed declines in groundwater-level elevations and streamflow, contemporaneous with increases in irrigation, have raised concerns about future groundwater availability and the effects of groundwater withdrawals on streamflow. To quantify the impacts of groundwater withdrawals on streamflow and increase understanding of groundwater and surface-water interaction in the MAP, hydrograph-separation techniques were used to estimate baseflow and identify statistical streamflow trends. The analysis was conducted using the US Geological Survey Groundwater Toolbox open-source software and daily hydrologic data provided by a spatially distributed network of paired groundwater wells and streamgage sites. This study found that statistically significant reductions in stream baseflow occurred in areas with substantial groundwater-level declines. The use of hydrograph-separation and trend analyses to quantify the impacts of groundwater withdrawals and the use of streamflow as a proxy for changes in groundwater availability may be applicable in other altered environments. Characterizing and defining hydrologic relations between groundwater and surface water will help scientists and water-resource managers refine a regional groundwater-flow model that includes the Mississippi Delta, which will be used to aid water-resource managers in future decisions concerning the alluvial aquifer.