This paper addresses the development of homogenized energy models which characterize the ferroelastic switching mechanisms inherent to ferroelectric materials in a manner suitable for subsequent transducer and control design. In the first step of the development, we construct Helmholtz and Gibbs energy relations which quantify the potential and electrostatic energy associated with 90 • and 180 • dipole orientations. Equilibrium relations appropriate for homogeneous materials in the absence or presence of thermal relaxation are respectively determined by minimizing the Gibbs energy or balancing the Gibbs and relative thermal energies using Boltzmann principles. In the final step of the development, stochastic homogenization techniques are employed to construct macroscopic models suitable for nonhomogeneous, polycrystalline compounds. Attributes and limitations of the characterization framework are illustrated through comparison with experimental PLZT data. Public reporting burden for the collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding this burden estimate or any other aspect of this collection of information, including suggestions for reducing this burden, to Washington Headquarters Services, Directorate for Information Operations and Reports, 1215 Jefferson Davis Highway, Suite 1204, Arlington VA 22202-4302. Respondents should be aware that notwithstanding any other provision of law, no person shall be subject to a penalty for failing to comply with a collection of information if it does not display a currently valid OMB control number.