Preparation of Transparent PVC-Titanosilicate Nanocomposites by Interlamellar Silylation of Layered Titanosilicate

Single- and Double-Layered Organically Modified Nanosheets by Selective Interlayer Grafting and Exfoliation of Layered Potassium Hexaniobate

“…Techniques developed for surface modification of metal oxide substrates have been applied to organic derivatization of inorganic layered compounds. Grafting reactions using trialkoxy- or trichlorosilanes (silylation) have been used extensively to modify crystalline layered silicic acids − and transition metal oxides. − Grafting reactions with alcohols and carboxylic acids (as carboxylate) have also been reported. − Organophosphonic acids, which allow grafting of a wide range of metal oxide substrates, , can also be employed for organic derivatization of inorganic layered compounds, and interlayer grafting reactions of protonated layered perovskite HLaNb 2 O 7 · x H 2 O with phenylphosphonic and alkylphosphonic acids have recently been achieved …”