2005
DOI: 10.1111/j.1551-2916.2005.00488.x
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Preparation of Sputtered (Bax,Sr1−x)TiO3 Thin Films Directly on Copper

Abstract: Ba 0.6 ,Sr 0.4 )TiO 3 (BST) films were deposited on copper foils by radio frequency magnetron sputtering. By the use of controlled pO 2 high-temperature anneals, the films were completely crystallized in the absence of substrate oxidation. X-ray diffraction and transmission electron microscopy (TEM) revealed an abrupt Cu/BST interface. The deposited BST films exhibit a zero bias permittivity and loss tangent values of 600 and 0.018, respectively. An electrical tunability ratio of 3.5:1 is observed on these met… Show more

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Cited by 35 publications
(29 citation statements)
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“…Processing compatibility between base-metal substrates and oxide fi lms has previously been demonstrated for coated conductor [ 15 ] and capacitor applications [16][17][18] using an equilibrium controlled-atmosphere approach. [ 19 ] Through careful control of the oxygen partial pressure during the high-temperature annealing steps, a processing space where base-metal substrates remain metallic and oxide fi lm constituents are oxidized can be found, as shown in Figure 1 for the lithium, lanthanum, tantalum, copper, and oxygen systems.…”
Section: Fast Lithium-ion Conducting Thin-film Electrolytes Integratementioning
confidence: 99%
“…Processing compatibility between base-metal substrates and oxide fi lms has previously been demonstrated for coated conductor [ 15 ] and capacitor applications [16][17][18] using an equilibrium controlled-atmosphere approach. [ 19 ] Through careful control of the oxygen partial pressure during the high-temperature annealing steps, a processing space where base-metal substrates remain metallic and oxide fi lm constituents are oxidized can be found, as shown in Figure 1 for the lithium, lanthanum, tantalum, copper, and oxygen systems.…”
Section: Fast Lithium-ion Conducting Thin-film Electrolytes Integratementioning
confidence: 99%
“…7 Recently, there has been extensive research on growing BST thin films on base-metal substrates to lower material cost. [10][11][12] Postdeposition annealing ͑400-750°C͒ in oxidizing ambient is necessary for making BST with a high dielectric constant, 12 but interfacial layers are introduced due to easy oxidation of base-metal electrodes, finally leading to a high EOT, which makes BST/base-metal stacks ineffective as well as complex to make.…”
mentioning
confidence: 99%
“…6. Compared with the prior report [7], the deposited thick-film exhibits high leakage current, which is mainly due to the existence of porosity certified by microstructure images in the inserts of Fig. 4.…”
Section: /[1228]mentioning
confidence: 71%