Preparation of sandwich-like phosphorus/reduced graphene oxide composites as anode materials for lithium-ion batteries

Wang, Liyuan; Guo, Hailong; Wang, Wei; Teng, Kunyue; Xu, Zhiwei; Chen, Cheng; Li, Cuiyu; Yang, Caiyun; Hu, Chuansheng

doi:10.1016/j.electacta.2016.06.052

Cited by 74 publications

(44 citation statements)

References 40 publications

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“…b) SEM image of the cross section of a P@GN paper, the inset shows its paper-like appearance. In this regard, Wang et al [158] proposed a facile high-pressure-assisted spraying strategy (Figure 7a), to realize the hybrids of reduced graphene oxide sheets (GS) and nanosized phosphorus particles (P@GS) with unique sandwich-like structure. d) Schematic illustration of the first sodiation-desodiation process of the P@GN nanosheet.…”

Section: Other Synthetic Methodsmentioning

confidence: 99%

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Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Wei

Zhang

et al. 2018

Advanced Energy Materials

163

128

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High‐performance and lost‐cost lithium‐ion and sodium‐ion batteries are highly desirable for a wide range of applications including portable electronic devices, transportation (e.g., electric vehicles, hybrid vehicles, etc.), and renewable energy storage systems. Great research efforts have been devoted to developing alternative anode materials with superior electrochemical properties since the anode materials used are closely related to the capacity and safety characteristics of the batteries. With the theoretical capacity of 2596 mA h g−1, phosphorus is considered to be the highest capacity anode material for sodium‐ion batteries and one of the most attractive anode materials for lithium‐ion batteries. This work provides a comprehensive study on the most recent advancements in the rational design of phosphorus‐based anode materials for both lithium‐ion and sodium‐ion batteries. The currently available approaches to phosphorus‐based composites along with their merits and challenges are summarized and discussed. Furthermore, some present underpinning issues and future prospects for the further development of advanced phosphorus‐based materials for energy storage/conversion systems are discussed.

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Section: Other Synthetic Methodsmentioning

confidence: 99%

Section: Other Synthetic Methodsmentioning

confidence: 99%

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Wei

Zhang

et al. 2018

Advanced Energy Materials

163

128

View full text Add to dashboard Cite

show abstract

“…As highly conductive 2D materials, many MXenes are capable of acting as scaffolds for materials which exhibit desirable electrochemistry but suffer poor electrical conductivity and/or large volume changes upon reaction with Li + . While carbon nanomaterials have been exploited for this purpose in a number of studies, MXenes are hydrophilic – meaning they can be processed in aqueous solvents – and are able to participate in a wide range of chemistry without sacrificing conductivity, allowing for composite components to be more thoroughly mixed and to be linked by stronger connections via in situ synthesis. One simple way to achieve this is to oxidise a carbide MXene and thus produce nanoparticles of an electrochemically active metal oxide on the surface of conductive carbon sheets.…”

Section: Li‐ion Batteriesmentioning

confidence: 99%

MXene‐Based Anodes for Metal‐Ion Batteries

Greaves

Barg

Bissett

2020

Batteries & Supercaps

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2D transition metal carbides and nitrides (MXenes) are electrochemically active materials capable of exhibiting pseudocapacitance. Multilayer MXenes are similar to graphite, but with larger interlayer spacing and surface functionalities which allow them to readily disperse in water and undergo a range of reactions without compromising their electrical conductivity. The large interlayer spacing enables MXenes to readily intercalate large ions, and form composites with materials such as graphene, metal oxides, transition metal dichalcogenides and silicon, with which they make electrodes able to deliver exceptional capacities at high power rates over thousands of cycles. Research into MXenes for energy storage has grown exponentially since 2011, and it is now necessary, especially for readers new to the field, to review progress made in more specific areas. This critical review will therefore analyse the progress made in developing MXene‐based batteries, focusing solely on anodes developed for metal‐ion batteries such as Li‐ion, Na‐ion and K‐ion.

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“…Nanostructuring and nanocomposites have been demonstrated to be effective in alleviating these issues. In particular, nanocomposites of nanosized RP and carbonaceous materials have been reported to able to improve the cell kinetics and suppress the volume-expansion-induced capacity fading [16,[20][21][22][23][24][25][26][27][28][29][30]. Highenergy mechanical ball milling and vaporization-condensation route are the two mostly reported strategies to achieve P/C nanocomposites.…”

Section: Introductionmentioning

confidence: 99%

Hierarchically porous carbon/red phosphorus composite for high-capacity sodium-ion battery anode

Feng

Liu

et al. 2018

Science Bulletin

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Preparation of sandwich-like phosphorus/reduced graphene oxide composites as anode materials for lithium-ion batteries

Cited by 74 publications

References 40 publications

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

MXene‐Based Anodes for Metal‐Ion Batteries

Hierarchically porous carbon/red phosphorus composite for high-capacity sodium-ion battery anode

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