Preparation of novel metal-carboxylate system MOF membrane for gas separation

Application of MD Simulations to Predict Membrane Properties of MOFs

“…These properties make MOFs attractive materials in several chemical applications such as gas storage [9], gas separation [10], catalysis [11], and drug delivery [12]. Among these areas, gas separation can be considered as the most mature one since a large number of experimental studies have been carried out for adsorption and membrane-based gas separations by MOFs [13][14][15]. If the appropriate metal complexes and organic ligands are chosen, MOFs with predefined pore sizes and shapes can be created for specific gas separations.…”

Metal organic frameworks for hydrogen purification

“…Other MOF materials that also contain multi-carboxylate include Zn2(cam)2dabco [83], Zn(BDC)(TED)0.5 [84], CAU-1 [85], CAU-10-H [86], etc. Their permeance and selectivities for different gases are in a similar range as the carboxylate containing MFOs mentioned above and shown in table 7.…”

“…Other MOF materials that have been reported for hydrogen separation (i.e. Zn2(cam)2dabco [83], Cu(hfipbb)(H2hfipbb)0.5 [124] , Cu2(bza)4(pyz) [125] , Ni-(4-pyridylcarboxylate)2 [126]) can be found in the references. Ni-(4-pyridylcarboxylate)2 is highlighted here due to its high CO2/H2 selectivities.…”

Preparation and characterization of Ni2(mal)2(bpy) homochiral MOF membrane

“…Compared with traditional separation technologies, such as high‐performance liquid chromatography, HMOF membrane‐based separation could offer greater potential applications in terms of its nature properties. However, the formation and fabrication of HMOF membranes on porous substrates remains a challenge, although a few attempts have been made . Generally, HMOF membranes can be synthesized via in situ synthesis or secondary growth method.…”