1991
DOI: 10.1002/app.1991.070431220
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Preparation of cation‐exchange starches containing phosphoric acid groups

Abstract: SYNOPSISPoly (glycidyl methacrylate) -starch graft copolymer was prepared using hydrogen peroxide/ ferrous sulphate/thiourea dioxide redox system as initiator. The copolymer was treated with orthophosphoric acid ( H3P04) under a variety of conditions to discover appropriate conditions for synthesizing the copolymer that can serve as cation exchanger. Results obtained indicated that the cation-exchange capacity is enhanced by: ( a ) increasing the H3P04/epoxy molar ratio up to 4; ( b ) using material-to-liquor … Show more

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Cited by 23 publications
(9 citation statements)
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“…30%) h‐ydroxyl groups, and the phosphate content of potato amylopectin is known to be higher than that of cereal amylopectin (Rooke et al ., 1949; Hizukuri et al ., 1970; Takeda & Hizukuri, 1982; Hizukuri, 1996). Starches that have acidic groups such as sulphate, phosphate, and carboxyl can behave as cation‐exchange starches (Khalil et al ., 1991; Khalil & Aly, 2002). These results suggest that starch molecules have binding sites for cations.…”
Section: Discussionmentioning
confidence: 99%
“…30%) h‐ydroxyl groups, and the phosphate content of potato amylopectin is known to be higher than that of cereal amylopectin (Rooke et al ., 1949; Hizukuri et al ., 1970; Takeda & Hizukuri, 1982; Hizukuri, 1996). Starches that have acidic groups such as sulphate, phosphate, and carboxyl can behave as cation‐exchange starches (Khalil et al ., 1991; Khalil & Aly, 2002). These results suggest that starch molecules have binding sites for cations.…”
Section: Discussionmentioning
confidence: 99%
“…There is a significant rise in moisture regain and especially in water uptake capacity with increase in percent of grafting. This increase could be attributed to the hydrophilic character of the poly(N-VP) side chains and increase in the number of hydrophilic groups on the starch upon increase in% grafting [32,33].…”
Section: Moisture Regain and Water Uptake Characteristicsmentioning
confidence: 99%
“…Since then, the ability of various other polysaccharides to yield inert, hydrophilic supports of well-defined dimensions has been widely utilized, both on a laboratory and an industrial scale, for the separation, fractionation and purification of a countless number of molecules. Sephadex is currently used for the industrial separation of plasma proteins such as albumin, immunoglobulins and blood factors [103], whereas anion and cation exchangers based on Sephade~, DEAE-(diethylaminoethyl-) and carboxymethyldextran, and starch [104] have been synthesized and used for the separation of charged molecules, such as proteins.…”
Section: Polysaccharides For Biotechnology Separatory Products and Lmentioning
confidence: 99%