“…Ferroelectric fluoropolymers are ideal candidates for the fabrication of mechanical energy scavengers and self-powered sensors, as they are characterized by mechanical flexibility, lightness, reversible piezo- and pyroelectric properties, and low energy consumption. , Among them, PVDF-based flexible piezoelectric nanogenerators (PENGs) attract significant interest in this field owing to their appreciable piezoelectric coefficient values, high flexibility, easy processing, and stability under high electric field. For achieving good piezoelectric performance in PVDF, it must be in the electroactive β-phase where the dipoles are oriented in the all-trans (TTTT) planar zig–zag conformation. − For obtaining and enhancing the β-phase of PVDF, several strategies such as new and improved fabrication techniques, ,,− incorporation of organic and inorganic piezoelectric materials such as ZnO, BaTiO 3 , , etc., and addition of conductive materials such as graphene, , CNT, etc. and nonconductive fillers such as nanoclay, , DNA, etc.…”