Towards the goal of improving the tribological properties of epoxy-based composites, epoxy resin was firstly modified with carboxyl terminated butadiene acrylonitrile (CTBN), and then further modified by core-shell structured of SiO 2 @MoS 2 fillers. The friction and wear properties of studied composites were tested on a Plate-on-Ring configuration under different loads and speeds. To reveal the tribological contribution of MoS 2 and SiO 2 in the hybrid fillers, tribo-tests were also done on composites filled with single CTBN, MoS 2 and SiO 2 . It is revealed that the transfer of both the EP/CTBN matrix and SiO 2 @MoS 2 CSs fillers play an important role in governing the tribo-properties of rubber toughened EP composites. Depending on contacting conditions, the SiO 2 @MoS 2 CSs fillers might be released into the sliding interface and tribochemical reactions might take place, both of which helped improve the triboproperties of studied composites.
K E Y W O R D Scarboxyl terminated butadiene acrylonitrile, epoxy resin, SiO 2 @MoS 2 , tribochemical reaction, wear resistance