Preparation and thermoelectric transport properties of high-performance p-type Bi2Te3 with layered nanostructure

Tang, Xinfeng; Xie, Wenjie; Han, Li; Zhao, Wenyu; Zhang, Qingjie; Niino, Masayuki

doi:10.1063/1.2425007

Cited by 347 publications

(233 citation statements)

References 23 publications

(25 reference statements)

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“…[80] According to solid state physical principles, the ZT value for bulk mate rials with a single parabolic band (SPB) along a certain direc tion can be given as: [4] The timeline for thermoelectric bulk materials with 2D structures, showing data from a superlattice, [8] SnSe, [11,[19][20][21] Bi 2 Te 3 , [12,14,16,17,[22][23][24][25][26][27][28][29][30][31][32][33][34][35][36][37][38][39][40][41] BiCuSeO, [12,[42][43][44][45][46][47][48][49][50][51][52][53][54][55][56] Na x CoO 2 , [57,58] Ca 3 Co 4 O 9 , [5...…”

Section: Strategies From Artificial Superlatticesmentioning

confidence: 99%

Promising Thermoelectric Bulk Materials with 2D Structures

2017

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Given that more than two thirds of all energy is lost, mostly as waste heat, in utilization processes worldwide, thermoelectric materials, which can directly convert waste heat to electricity, provide an alternative option for optimizing energy utilization processes. After the prediction that superlattices may show high thermoelectric performance, various methods based on quantum effects and superlattice theory have been adopted to analyze bulk materials, leading to the rapid development of thermoelectric materials. Bulk materials with two‐dimensional (2D) structures show outstanding properties, and their high performance originates from both their low thermal conductivity and high Seebeck coefficient due to their strong anisotropic features. Here, the advantages of superlattices for enhancing the thermoelectric performance, the transport mechanism in bulk materials with 2D structures, and optimization methods are discussed. The phenomenological transport mechanism in these materials indicates that thermal conductivities are reduced in 2D materials with intrinsically short mean free paths. Recent progress in the transport mechanisms of Bi2Te3‐, SnSe‐, and BiCuSeO‐based systems is summarized. Finally, possible research directions to enhance the thermoelectric performance of bulk materials with 2D structures are briefly considered.

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Section: Strategies From Artificial Superlatticesmentioning

confidence: 99%

Promising Thermoelectric Bulk Materials with 2D Structures

2017

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“…The detailed process can be found elsewhere. 18,26,27 The resulting ribbon-shaped samples were ground into powders in an agate mortar and then sintered by SPS at 900 K under a pressure of 50 MPa to obtain densified bulk samples.…”

Section: Methodsmentioning

confidence: 99%

Electrical and thermal transport properties of Y bxCo4Sb12 filled skutterudites with ultrahigh carrier concentrations

Qiu

Xiong³

et al. 2015

AIP Advances

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For filled skutterudites, element Yb is one of the most common and important fillers. However, the optimal carrier concentration range in Y bxCo4Sb12 filled skutterudites has not been determined as a result of the low Yb filling fraction limit. In this study, a non-equilibrium fabrication process (MS-SPS process), consisting of a melt-spinning method and a spark plasma sintering technique, has been applied to prepare Y bxCo4Sb12 samples. The Yb filling fraction is successfully extended to 0.35, which provides the possibility to clarify the optimal carrier concentration range for Yb-filled skutterudites. High carrier concentrations, with a maximum of around 1 × 1021 cm−3, were achieved in the MS-SPS Y bxCo4Sb12 samples due to the significantly enhanced Yb filling fractions. The phase compositions, lattice parameters, electrical and thermal transport properties of the MS-SPS Y bxCo4Sb12 samples with high carrier concentrations were systematically investigated. An optimal carrier concentration range of around 5 ∼ 6 × 1020 cm−3, corresponding to the actual Yb filling fraction of around 0.21∼0.26, has been determined, which displays the highest thermoelectric performance in Y bxCo4Sb12 thermoelectric materials.

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“…Usually, inorganic materials, such as PbTe, Bi 2 Te 3 and Cu 2 Se, have ordered crystalline structures and better electron transport than organic materials. [6][7][8][9][10] In conventional conducting polymers, the inter-chain and intra-chain π-π conjugations form the carrier transport channels. The carrier transport is principally controlled by the inter-chain and intra-chain hopping processes and follows the variable range hopping model.…”

Section: Introductionmentioning

confidence: 99%

Highly anisotropic P3HT films with enhanced thermoelectric performance via organic small molecule epitaxy

et al. 2016

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Conducting polymers are potential candidates for thermoelectric (TE) applications owing to their low thermal conductivity, non-toxicity and low cost. However, the coil conformation and random aggregation of polymer chains usually degrade electrical transport properties, thus deteriorating TE performance. In this work, we fabricated poly(3-hexylthiophene) (P3HT) films with highly oriented morphology using 1,3,5-trichlorobenzene (TCB), an organic small-molecule, as a template for polymer epitaxy under a temperature gradient crystallization process. The resulting P3HT molecules, which were confirmed to be highly anisotropic by a combination of scanning electron microscopy, atomic force microscopy, polarizing microscope, polarized Raman spectroscopy, and two-dimensional-grazing incidence X-ray diffraction (GIXRD) analysis, not only markedly reduced the conjugated defects along the polymer backbone, but also effectively increased the degree of electron delocalization. These combined phenomena produced an efficient, 1D path for carrier movement and therefore resulted in enhanced carrier mobility in the TCB-treated P3HT films. The maximum values of the electrical conductivity and Seebeck coefficient were 320 S cm À1 and 269 μV K À1 , respectively. Consequently, the maximum TE power factor and ZT value at 365 K reached 62.4 μW mK À2 and 0.1, respectively, in the parallel direction of the TCB-treated P3HT film. To the best of our knowledge, these are the highest values reported for pure P3HT TE materials. The method of using organic small-molecule epitaxy to generate highly anisotropic polymer films is expected to be valid for many conducting polymers.

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Preparation and thermoelectric transport properties of high-performance p-type Bi2Te3 with layered nanostructure

Cited by 347 publications

References 23 publications

Promising Thermoelectric Bulk Materials with 2D Structures

Promising Thermoelectric Bulk Materials with 2D Structures

Electrical and thermal transport properties of Y bxCo4Sb12 filled skutterudites with ultrahigh carrier concentrations

Highly anisotropic P3HT films with enhanced thermoelectric performance via organic small molecule epitaxy

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