Preparation and multifunction of electrochromic polyamides containing flexible backbone chains with electrochemical, fluorescence and memory properties
“…14 containing four pyridinium salt units 15 or four benzoic acid ester units 16 connected through a cyclobutane ring have been reported to demonstrate one bleached and two colored states. Finally, organic molecules containing triarylamine 4,17 and carbazole 18,19 moieties seem to be promising candidates for multicolored ECDs. Metalorganic polypyridine complexes are considered ideal chromophores for the design of ECDs due to their ability to react with many metal ions in different oxidation states, 20−22 excellent cycling 23,24 and thermal stability, 25,26 flexibility, 27,28 color diversity, 29 and light absorption, which strictly depends on metal oxidation state.…”
Section: ■ Introductionmentioning
confidence: 99%
“…Organic molecules containing four pyridinium salt units or four benzoic acid ester units connected through a cyclobutane ring have been reported to demonstrate one bleached and two colored states. Finally, organic molecules containing triarylamine , and carbazole , moieties seem to be promising candidates for multicolored ECDs.…”
The
article describes novel electrochromic materials (ECMs) that are based
on a monolayer consisting of two or three isostructural metal complexes
of 4′-(pyridin-4-yl)-2,2’:6′,2’’-terpyridine
simultaneously deposited on surface-enhanced support. The support
was made by screen printing of indium tin oxide (ITO) nanoparticles
on ITO-glass and has a surface area sufficient for a monolayer to
give color visible to the naked eye. The ability to separately electrochemically
address the oxidation state of the metal centers on the surface (i.e.,
Co2+/Co3+, Os2+/Os3+,
and Fe2+/Fe3+) provides an opportunity to achieve
several distinct color-to-color transitions, thus opening the door
for constructing monolayer-based multicolor ECMs.
“…14 containing four pyridinium salt units 15 or four benzoic acid ester units 16 connected through a cyclobutane ring have been reported to demonstrate one bleached and two colored states. Finally, organic molecules containing triarylamine 4,17 and carbazole 18,19 moieties seem to be promising candidates for multicolored ECDs. Metalorganic polypyridine complexes are considered ideal chromophores for the design of ECDs due to their ability to react with many metal ions in different oxidation states, 20−22 excellent cycling 23,24 and thermal stability, 25,26 flexibility, 27,28 color diversity, 29 and light absorption, which strictly depends on metal oxidation state.…”
Section: ■ Introductionmentioning
confidence: 99%
“…Organic molecules containing four pyridinium salt units or four benzoic acid ester units connected through a cyclobutane ring have been reported to demonstrate one bleached and two colored states. Finally, organic molecules containing triarylamine , and carbazole , moieties seem to be promising candidates for multicolored ECDs.…”
The
article describes novel electrochromic materials (ECMs) that are based
on a monolayer consisting of two or three isostructural metal complexes
of 4′-(pyridin-4-yl)-2,2’:6′,2’’-terpyridine
simultaneously deposited on surface-enhanced support. The support
was made by screen printing of indium tin oxide (ITO) nanoparticles
on ITO-glass and has a surface area sufficient for a monolayer to
give color visible to the naked eye. The ability to separately electrochemically
address the oxidation state of the metal centers on the surface (i.e.,
Co2+/Co3+, Os2+/Os3+,
and Fe2+/Fe3+) provides an opportunity to achieve
several distinct color-to-color transitions, thus opening the door
for constructing monolayer-based multicolor ECMs.
“…35,36 For a better understanding of the working of the memory devices, theoretical calculations using Gaussian 09 were carried out to consider the charge transfer and trapping in the compounds. 13 The HOMO of the compounds 14a-b is located in the triarylamine molecule whereas the compounds 14c-d have electron density throughout the backbone (Fig. 8).…”
Section: Resistive Switching Mechanismmentioning
confidence: 99%
“…12 Resistive random access memory (RRAM) especially has a huge advantage over the conventional memory devices as it solves the limitations like high production cost, high power consumption, complex processes of manufacturing, etc. 13 A typical RRAM device is a sandwiched structure with a resistive switching material between two terminal electrodes. 14 Memory characteristics are achieved by fine-tuning the applied voltages and the threshold voltage, on/off ratio, endurance cycle, and retention time are measured from the current-voltage curves, which indicate the memory behavior of the systems.…”
A series of D-A-D architectured molecules with quinoline as the central core and triarylamines (TAA) at both terminals were synthesized and studied for their memory performance. The photophysical studies exhibited...
“…Generally, PAs are resistant to solvents, fuels, and lubricants. However, they are not inherently flame retardant [ 130 , 131 , 132 , 133 , 134 , 135 , 136 , 137 , 138 , 139 ].…”
The three-dimensional molded interconnected device (3D-MID) has received considerable attention because of the growing demand for greater functionality and miniaturization of electronic parts. Polymer based composite are the primary choice to be used as substrate. These materials enable flexibility in production from macro to micro-MID products, high fracture toughness when subjected to mechanical loading, and they are lightweight. This survey proposes a detailed review of different types of 3D-MID modules, also presents the requirement criteria for manufacture a polymer substrate and the main surface modification techniques used to enhance the polymer substrate. The findings presented here allow to fundamentally understand the concept of 3D-MID, which can be used to manufacture a novel polymer composite substrate.
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